Hello Adrian,
maybe one of the installed source files lead
to a bad gschemas.compiled file?

Could you create a file with the md5sums of all
the xml files that seem to get combined into that
gschemas.compiled file.

     md5sum /usr/share/glib-2.0/schemas/* > 
~/usr-share-glib-2.0-schemas-md5sums.txt

Also you may attach the gschemas.compiled too?

Kind regards,
Bernhard

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