i don't understand why it can't connect, this seems to work fine:

fine ?

you're manually overriding at least one problem with your certs/config

...
- Status: The certificate is NOT trusted. The name in the certificate does not 
match the expected.
*** PKI verification of server certificate failed...
Host 10.0.0.91 (sieve) has never been contacted before.
Its certificate is valid for 10.0.0.91.
Are you sure you want to trust it? (y/N): y
...

it appears that you're using a self-signed cert?  are your trusted certs 
defined and correctly chained?  if not explicitly defined, did you correctly 
add you certs to system ssl dirs, and ensure hashes are correct?

demonstrate first that you can connect to dovecot over tls with a cmd line 
client, without ignoring or overriding your cert problems

including any client/server cert verification requirements you've turned on in 
dovecot config

once you've passed the correct certs, then demonstrate that you can 
authenticate in the same session with any password/credentials you've set

once that all works, make sure you've got those certs correctly set up in your 
rc config


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