Yes, now we are on the same page!

On Thu, Oct 10, 2024, 2:44 PM Sergio Ciordia <[email protected]> wrote:

> Hi David,
>
> I have anticipated your answer and I think this is what you asked for. I
> have used TPP to generate the DECOY database using these settings:
>
> [image: image.png]
>
> I have searched PEAKS again and uploaded the new file ‘
> PEAKS_target_decoy.pep.xml’ and the decoy database to the shared folder.
>
> Link: PEAKS Dataset
> <https://drive.google.com/drive/folders/1Q3LF1wRTM62KfS20dfXmToQMY9ji9Dug>
>
> See what you think of the output.
>
> Best,
> Sergio
>
> --------------------------
> Sergio Ciordia Higuera
> Proteomics Facility
> National Center for Biotechnology
> C\Darwin, 3
> Universidad Autónoma de Madrid
> Cantoblanco
> 28049 Madrid (Spain)
> Phone: +34 91 585 4540 / 4695
> Fax: +34 91 585 4506
>
>
> El jue, 10 oct 2024 a las 22:47, Sergio Ciordia (<[email protected]>)
> escribió:
>
>> OK, I think I understand you now. I think what you are asking me to do is
>> to create a database containing the target and decoy entries and repeat the
>> search. Then in the output that PEAKS gives us, we could locate the
>> ‘unknown’ decoy. Is this what you need?.
>>
>> Sergio
>>
>> --------------------------
>> Sergio Ciordia Higuera
>> Proteomics Facility
>> National Center for Biotechnology
>> C\Darwin, 3
>> Universidad Autónoma de Madrid
>> Cantoblanco
>> 28049 Madrid (Spain)
>> Phone: +34 91 585 4540 / 4695
>> Fax: +34 91 585 4506
>>
>>
>> El jue, 10 oct 2024 a las 22:33, 'David Shteynberg' via spctools-discuss
>> (<[email protected]>) escribió:
>>
>>> I think we have a bit of misunderstanding here.  I am not looking for
>>> decoys that are "known" to PEAKS,  I want to include entrapment decoys that
>>> are "unknown" to PEAKS and known to us as true negatives.  Then we can
>>> utilized the true negatives to estimate error rates.  The true negative
>>> entrapment decoys should not be revealed to the search algorithm, just like
>>> the false positives among the target sequences are not known to the
>>> algorithm, but represent the error we are trying to control.
>>>
>>> I hope this makes sense.
>>>
>>> -David
>>>
>>> On Thu, Oct 10, 2024 at 10:48 AM Sergio Ciordia <[email protected]>
>>> wrote:
>>>
>>>> Hi David,
>>>>
>>>> There are several commercial softwares such as PEAKS or Proteome
>>>> Discoverer that you upload the target database directly and they internally
>>>> generate the Target-Decoy database. The problem is that when you launch the
>>>> search and get the output, the software usually removes the decoy entries
>>>> from the final results and that's why they don't appear in the list.
>>>>
>>>> I understand then that we would need the same ‘pep.xml’ file but
>>>> containing all the target and decoy entries. Is that what you need?.
>>>>
>>>> Best,
>>>> Sergio
>>>>
>>>> --------------------------
>>>> Sergio Ciordia Higuera
>>>> Proteomics Facility
>>>> National Center for Biotechnology
>>>> C\Darwin, 3
>>>> Universidad Autónoma de Madrid
>>>> Cantoblanco
>>>> 28049 Madrid (Spain)
>>>> Phone: +34 91 585 4540 / 4695
>>>> Fax: +34 91 585 4506
>>>>
>>>>
>>>> El jue, 10 oct 2024 a las 19:40, 'David Shteynberg' via
>>>> spctools-discuss (<[email protected]>) escribió:
>>>>
>>>>> Hello Sergio,
>>>>>
>>>>> Thanks for sending this. After taking a look I have another request.
>>>>> The database you searched against seems to not contain any entrapment
>>>>> DECOYS to help independently validate any computed scores or
>>>>> probabilities.  Are you able to search this data against a database
>>>>> containing some decoys?  You can use the TPP decoy generator to create
>>>>> decoys (we have been using deBruijn randomized sequences), or should I
>>>>> create it and give you the database to search?
>>>>>
>>>>> Best,
>>>>> -David
>>>>>
>>>>> On Thu, Oct 10, 2024 at 3:52 AM Sergio Ciordia <[email protected]>
>>>>> wrote:
>>>>>
>>>>>> Thank you David. You are right, I attach in this new link the 3 files
>>>>>> you need: mzML, fasta and pep.xml.
>>>>>>
>>>>>> Link: PEAKS Dataset
>>>>>> <https://drive.google.com/drive/folders/1Q3LF1wRTM62KfS20dfXmToQMY9ji9Dug>
>>>>>>
>>>>>> I hope you can do something. Thanks anyway for your concern.
>>>>>>
>>>>>> Best regards,
>>>>>> Sergio
>>>>>>
>>>>>> --------------------------
>>>>>> Sergio Ciordia Higuera
>>>>>> Proteomics Facility
>>>>>> National Center for Biotechnology
>>>>>> C\Darwin, 3
>>>>>> Universidad Autónoma de Madrid
>>>>>> Cantoblanco
>>>>>> 28049 Madrid (Spain)
>>>>>> Phone: +34 91 585 4540 / 4695
>>>>>> Fax: +34 91 585 4506
>>>>>>
>>>>>>
>>>>>> El jue, 10 oct 2024 a las 1:34, David Shteynberg (<
>>>>>> [email protected]>) escribió:
>>>>>>
>>>>>>> Thank you Sergio!  Would you mind also sending the mzML data and the
>>>>>>> sequence database that goes along with these search results from PEAKS?
>>>>>>>
>>>>>>> Best,
>>>>>>> -David
>>>>>>>
>>>>>>> On Oct 9, 2024, at 3:58 PM, Sergio Ciordia <[email protected]>
>>>>>>> wrote:
>>>>>>>
>>>>>>> Hi David,
>>>>>>>
>>>>>>> Thank you for your quick and honest response. I am sorry to hear
>>>>>>> that you have no funds to continue TPP implementation. I hope this 
>>>>>>> problem
>>>>>>> will be solved.
>>>>>>> Nevertheless, I appreciate your consideration of evaluating a sample
>>>>>>> file. This file contains what the PEAKS team calls ‘Peptide output in
>>>>>>> pepxml’. I hope it is adequate but in any case I don't think there will 
>>>>>>> be
>>>>>>> a problem in getting a suitable data output for TPP if necessary. The 
>>>>>>> other
>>>>>>> format that can be obtained is mzidentML in case it is of interest.
>>>>>>>
>>>>>>> LINK: pepXML PEAKS sample
>>>>>>> <https://drive.google.com/file/d/185t5m7vJPLQAj8vVpcviX_p58DHZfyAB/view?usp=sharing>
>>>>>>>
>>>>>>> Thanks again for your reply.
>>>>>>>
>>>>>>> Best regards,
>>>>>>> Sergio
>>>>>>>
>>>>>>> --------------------------
>>>>>>> Sergio Ciordia Higuera
>>>>>>> Proteomics Facility
>>>>>>> National Center for Biotechnology
>>>>>>> C\Darwin, 3
>>>>>>> Universidad Autónoma de Madrid
>>>>>>> Cantoblanco
>>>>>>> 28049 Madrid (Spain)
>>>>>>> Phone: +34 91 585 4540 / 4695
>>>>>>> Fax: +34 91 585 4506
>>>>>>>
>>>>>>>
>>>>>>> El jue, 10 oct 2024 a las 0:46, David Shteynberg (<
>>>>>>> [email protected]>) escribió:
>>>>>>>
>>>>>>>> Hello Sergio,
>>>>>>>>
>>>>>>>> Thank you for your email.  As you know PEAKS is not a search engine
>>>>>>>> that we have integrated in the TPP, mainly because we have not had any
>>>>>>>> requests for this feature before your email.  It is something that can 
>>>>>>>> be
>>>>>>>> done with a bit of work and testing, but unfortunately there is 
>>>>>>>> currently
>>>>>>>> no funding for us to continue this work.  I wish I had a more 
>>>>>>>> satisfying
>>>>>>>> answer to give you, but perhaps, if you can forward your sample pep.xml
>>>>>>>> file, we can do this if more funding becomes available.
>>>>>>>>
>>>>>>>> Best,
>>>>>>>> -David
>>>>>>>>
>>>>>>>> On Oct 9, 2024, at 3:35 PM, Sergio Ciordia <[email protected]>
>>>>>>>> wrote:
>>>>>>>>
>>>>>>>> Hi,
>>>>>>>>
>>>>>>>> I have been using TPP for some time now mainly to validate with
>>>>>>>> PeptideProphet the results I get with various search engines and to
>>>>>>>> generate a spectral library that I use in various programs. The thing 
>>>>>>>> is
>>>>>>>> that in my lab we are now using PEAKS (v12) and the output is really 
>>>>>>>> good.
>>>>>>>> I was wondering if it would be possible to include in TPP an analysis
>>>>>>>> pipeline of the PEAKS data from the pep.xml file generated by the 
>>>>>>>> program.
>>>>>>>> I know it is a commercial software but the output is very good and
>>>>>>>> I would be very grateful if you could consider including it like 
>>>>>>>> Sequest or
>>>>>>>> Mascot. I think it would not be complicated since they already have the
>>>>>>>> pep.xml output, it would only have to be compatible with XInteract to 
>>>>>>>> be
>>>>>>>> able to validate peptide-spectrum matches.
>>>>>>>>
>>>>>>>> If necessary I can provide a sample pep.xml file.
>>>>>>>>
>>>>>>>> Thank you very much.
>>>>>>>>
>>>>>>>> Best regards,
>>>>>>>> Sergio
>>>>>>>>
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