Back when I was a full-time IBMer, I had a spreadsheet with all z/Architecture instructions sorted by the machine in which they were introduced. Unfortunately, this included IBM-confidential instructions, and I was not able to take it with me when I retired.
I recently spent a few hours massaging the instruction list in Appendix B3 of the z/Architecture Principles of Operation, and correlating the facility codes listed with the machine in which the instruction was introduced. You can find the results in a spreadsheet on my Google drive: https://docs.google.com/spreadsheets/d/1aU-4ndTXTEf17hCDLiqSqXfFENr39rIV/edit?usp=sharing&ouid=104012833061983447284&rtpof=true&sd=true Note, there may be some inaccuracies for instructions that were added by a mid-life kicker, for which the documentation did not appear until the next major machine was released.
