On Wed, 29 Jul 2015, drlegendre . wrote:
On Wed, Jul 29, 2015 at 5:19 PM, Fred Cisin <ci...@xenosoft.com> wrote:
On Wed, 29 Jul 2015, drlegendre . wrote:

Incidentally, what exactly differentiates a computer-grade cap from any other alum. electrolytic?

Maybe computer-grade don't need gold-plated oxygen-free leads?

I get the jab you're taking at latter-day Audiophool idiocy, but you won't find any gold-plated OFC business in any of the vintage gear I typically work with.

But as far as gold plating goes, gold is a good conductor, it solders very well, it doesn't tarnish and its ductility promotes solid connections on screw terminals - it's really these characteristics that make it somewhat desirable in certain applications. So it's not so much that gold "sounds better", it's that it allows one to make connections that work better. But it does tend to wear quickly.

While I don't want to go /too/ OT here, I do want to clear up one common misconception regarding gold plating. It isn't that gold itself wets easily when soldering...the tin content of the solder actually dissolves the gold and the solder bonds to the underlying metal surface.

This can also lead to gold embrittlement of the solder joint, and while it generally wasn't as big of an issue with larger through-hole solder joints (such as with older semiconductors which had gold plated leads), it did become a major issue for SMD boards with gold plated pads, and especially with BGA components.

This is why in high reliability applications, industry practice has been to pre-tin gold plated surfaces which are to be soldered, using a two step solder bath. The first being more sacrificial which will collect much of the gold, and a second to catch anything which might still be left.

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