In response to Fiona McLees's question about pH-induced color shifts in organic 
colorants on paper.  I have seen the leaching of blue colorant from Japanese 
woodblock prints into buffered matboards.  It's been difficult to photograph as 
it has been very subtle but I could try to send pictures off-line. Since I 
wasn't monitoring the prints over time I have no way of knowing if there was an 
actual color shift in the original prints, but there was certainly some sort of 
reaction.  I have saved the matboard but have not had the opportunity to 
analyze nor research. One of my questions would be whether problems are due to 
contact with buffered materials (I'm assuming this) or off-gassing from 
buffered materials (would like info on this) and would like some clarity.

Because of this, and all the other anecdotal recommendations about using 
unbuffered mounting and housing materials with organic colored materials, we 
keep all of our Japanese woodblock prints in unbuffered folders and mat in 
unbuffered matboard.  A side issue is that unbuffered matboard is getting 
difficult to find in any colors other than bright white (for photographs).

I think this is a really important area of study and hope to hear, Fiona, that 
you are taking this up as a project!

Emily Klayman Jacobson
Paper & Photographs Conservator
Freer Gallery of Art and Arthur M. Sackler Gallery
Smithsonian Institution
[email protected]
202.633.0374

__________________________________________________________
Message: 11
Date: Thu, 4 Apr 2019 08:04:47 +0000
From: Fiona Mclees <[email protected]>
Subject: [Consdistlist] pH-induced colour shifts in organic dyes and
                pigments on paper
Message-ID: <[email protected]>
Content-Type: text/plain; charset="utf-8"

There are many studies concerning light-induced fading of organic dyes and 
pigments on paper, but does anyone know of any research regarding the risk of 
pH-induced colour shifts in organic colourants on paper? The internet offers 
some recommendations that unbuffered mounting and housing materials should be 
used in proximity to watercolours and hand-tinted prints (for example, see 
https://nam02.safelinks.protection.outlook.com/?url=https%3A%2F%2Fwww.nps.gov%2Fmuseum%2Fpublications%2Fconserveogram%2F04-09.pdf&amp;data=02%7C01%7Cjacobsone%40si.edu%7C3062bb20ff0b41ca7e4308d6b9b649dd%7C989b5e2a14e44efe93b78cdd5fc5d11c%7C1%7C1%7C636900589922278280&amp;sdata=Ko5pUudKR9bf%2BAiEGWWhv7iOHDQ4sQvkWQpvQWCerG8%3D&amp;reserved=0)
 but has anyone conducted research in this area, or observed colour change 
occurring due to alkaline-buffered storage materials?

Fiona McLees, ACR
Paper Conservator
Conservation & Collection Care
Weston Library
The Bodleian Libraries
Broad Street
Oxford OX1 3BG
Tel: +44 (0) 1865 277080
[email protected]<mailto:[email protected]>

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