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ONAMI <http://www.nanotech-now.com/columns/?column=07> > Nano and The New
Era: the Best of Times or the Worst of Times? How Green Nanoscience will
Help Decide

   Skip Rung
President and Executive Director
ONAMI <http://www.onami.us/>

*Abstract:*
In an unprecedented national environment where science funding is going up
and business confidence is plummeting, green nanoscience research is as
promising - and as necessary - as ever. Two new nanotechnology approaches to
advanced thin films with breakthrough performance and reduced environmental
footprint are highlighted.

January 25th, 2009 Nano and The New Era: the Best of Times or the Worst of
Times? How Green Nanoscience will Help Decide Among the many discouraging
recent news stories of layoffs and business failures, one from last week's
Sunday paper really got to me:

http://www.gazettetimes.com/articles/2009/01/18/news/top_story/1aaa01_toyregs.txt

Once again, thanks to a nearly unanimous vote of Congress and a(n
ex-)president's signature, many small American manufacturers and retailers
are facing shutdown in the wake of a sweeping over-reaction to an
over-reported news story on Chinese imports. Mattel, Wal-Mart and other
large corporations/big box stores have the means ($$ and knowhow) to comply,
but poor Mom and Pop do not. Maybe there will be a congressional reprieve
before February 10, and maybe there won't, but I hope those clamoring for
more "governance" of nanotechnology are at least a little worried about what
they might get. Making life more difficult than it already is for the
startups and spinouts who commercialize most advances, and escalation of the
risk faced by their investors are the last things anyone should want when
the economy is in free fall.

But there is at least some undeniable good news in the upcoming stimulus
package: about 1% of it will fund a 50% increase in science research, and
there is encouraging language that appears to understand why scientific
research and commercialized innovation are so important in both the short
term (something to excite investors again) and the longer term (growth of
durable companies and high-wage jobs).

However, the ongoing meltdown in business confidence and venture capital,
especially early stage, is unprecedented, and no one seems to really know
what to do (short of letting the credit hangover run its course, however
long that takes) to get it going again. But I don't think more rules and
regulations is the change we've been waiting for. I hope the administration
and congressional architects of the stimulus will think long and hard about
what (like sweeping regulation with unintended consequences) might thwart
the harvesting of results into jobs from the research in renewable energy,
healthcare and sustainable technology advances we are at last about to
accelerate.

Meanwhile, back at ONAMI, we are working away with great enthusiasm on our
three-pronged Green Nanotechnology program - described at
http://greennano.org - pursuing good ideas and opportunities that we hope
can outrace or at least greatly improve possible bad "governance" of the
aforementioned ilk.

I've written before in this column about our research on (1) rational design
of inherently safer nanomaterials (including sophisticated approaches to
understanding interactions with biological systems) and (2) environmentally
friendly/more efficient (material, energy, water) means of producing the
same. In the remainder of this column, I'd like to give two examples of our
"Thrust Group (3)" work: greener methods for interfacing nanoparticles and
nanostructures for device applications. In both cases, nanotechnology
breakthrough methods for advanced thin-film production have resulted in
recent large federal research awards. And in both cases, lower cost, lower
energy and lower waste solution chemistry methods promise to achieve what
has so far been possible only with expensive and inefficient vacuum
deposition techniques.

Microreactor-Assisted Nanomaterials Deposition (MAND) is a completely new
method using real-time mixing in microchannel reactors followed by direct
deposition for incorporating nanoparticles, nanorods, clusters etc.. into
thin films with useful features such as graded refractive indices, enhanced
nucleation/heat transfer, semiconducting properties or outstanding
antireflective coating performance (figure courtesy C.H. Chang, B.K. Paul).

    The MAND approach to nanomanufacturing


A new $2M U.S. Department of Energy Industrial Technologies Program project
involving researchers from PNNL, OSU, CH2M Hill and Voxtel Inc. will build
on early MAND results to develop a nanomanufacturing process which will
reduce the manufacturing energy, environmental discharge, and production
cost associated with current nano-scale thin-film photovoltaic (PV)
manufacturing approaches. A secondary objective is to use a derivative of
this nanomanufacturing process to enable greener, more efficient
manufacturing of higher efficiency quantum dot-based photovoltaic cells now
under development.

A second approach to novel material discovery and advanced thin films for
printed electronics, photovoltaics and other applications builds on the
well-known transparent transistor and solution-processed atomically dense,
atomically smooth inorganic thin film work (including nanolaminates). The
addressable range of solution-processable inorganic materials can be greatly
expanded through the use of metal nanoclusters as precursors (figure
courtesy of D.W. Johnson, D.A. Keszler).

    Green nanomaterials chemistry for advanced thin films


The Center for Green Materials Chemistry at OSU/UO is a Phase I Center for
Chemical Innovation (CCI) sponsored by the National Science Foundation
Division of Chemistry. The Center's research efforts are focused on the
study and development of new solution-based materials and process
chemistries that provide direct pathways to the deposition of dense,
high-quality inorganic films. The materials and methods circumvent problems
associated with conventional sol-gel deposition and the use of
nanoparticle-based inks, providing the means to realize film qualities
comparable to the most advanced vapor-deposition methods. Efforts involve
the study and use of environmentally benign materials and their deployment
through printing processes for efficient materials use.

We'll be sharing and discussing this kind of research and much more at our
March 2-3 ONAMI Greener Nano Conference in Eugene, OR - at the world's
premier quantum dot industry R&D and manufacturing location - the Molecular
Probes site of Invitrogen Corp. (recently merged with Applied Biosystems to
create Life Technologies). Take a look at the outstanding keynote speaker
program at:

http://oregonstate.edu/conferences/greenernano2009/program.htm


http://www.nanotech-now.com/columns/?article=272

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