I had a similar problem with synaptic 0.81.1ubuntu1 after doing an ubuntu
upgrade from 12.04 Precise to 14.04.1 Trusty

E: The value 'stable' is invalid for APT::Default-Release as such a release
is not available in the sources
E: _cache->open() failed, please report.

Removing the line that mentioned "stable" from
/root/.synaptic/synaptic.conf allowed synaptic to run without problems.
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Thank you,
David
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