Try this: 1. Close all programs that could be using sound (Iceweasel, players, etc.) 2. Set the volume as you want it. 3. rm -r ~/.pulse/ 4. reboot
See if your sound settings are carried through. That proved to be the solution for several of my systems. I don't know what precisely went wrong. It wasn't as simple as installing pulseaudio, but rather started when some other update went through when pulseaudio was installed. It is possible the "other update" was gnome-media (2.22 -> 2.24), as the timing was right; rebooting or not between the updates made no difference, but I ran out of computers needing updates before I could pin it down to the exact package, and didn't have the time to invest to downgrade and re-upgrade progressively.
I should also point out that I only ever had the mute problem on reboot, not just logging out and back in. On the other hand, if I rebooted but then logged into a failsafe terminal rather than my normal gnome session, the sound settings would be fine (checking via alsamixer) until I closed the terminal and proceeded to normal login (at which point my master or front, depending on the system, would be set to 0%/mute). I tried all kinds of fixes related to alsa that had absolutely no effect. This also solved a problem where I would usually get sound from programs, but the test pipes in Preferences -> Sound would fail when "autodetect" was selected for any given setting.
I think this is just a configuration issue/conflict between pulseaudio and some gnome component, but can't give any more information at this point or have any idea if it will occur again.
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