I don't know how to set this from any setting tool.
On my system there is the file ".local/share/applications/mimeapps.list"
containing the following lines

[Default Applications]
text/html=firefox.desktop
text/xml=firefox.desktop
x-scheme-handler/mailto=icedove.desktop
x-scheme-handler/http=firefox.desktop
x-scheme-handler/https=firefox.desktop
x-scheme-handler/ftp=firefox.desktop


Regards,
jvp.


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