What version of Xfce are you running? The screenshot given,
http://www.xfce.org/images/about/screenshots/4.6-2.png, is for Xfce 4.6,
I think. You can use 'apt-cache policy xfce4-session' in a terminal or
click on the Menu -> About Xfce, Info tab to find out for sure.
** Changed in: brasero (Ubuntu)
Status: New => Incomplete
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[XFCE] Brasero does not launch from menu
https://bugs.launchpad.net/bugs/336366
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