install dconf-tools
run 'dconf-editor' 
select org.gnome.desktop.background
run gnome-control-center, select background color.

dconf Editor immediately show changed values :

Name: primary-color
Value:rgb(138,226,52)
Type: String
Default: '#023c88'

Name: secondary-color
Value: rgb(206,92,0)
Type: String
Default: '#5789ca'

default color value is '#RRGGBB' style, but gnome-control-center set 
'rgb(dd,dd,dd)' style.
close gnome-control-center, set '#RRGGBB' manually via dconf-editor, then 
Desktop background color change successfully.

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Desktop Bugs, which is subscribed to gnome-control-center in Ubuntu.
https://bugs.launchpad.net/bugs/1138251

Title:
  Desktop wallpaper Colors & Gradients will not change color

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https://bugs.launchpad.net/ubuntu/+source/gnome-control-center/+bug/1138251/+subscriptions

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