I also having this bug. System is not shutting down properly. 
syslog file:
May 23 22:43:22 jsm NetworkManager[666]: <info> (ttyACM0): device state change: 
activated -> disconnected (reason 'user-requested') [100 30 39]
May 23 22:43:22 jsm NetworkManager[666]: <info> (ttyACM0): deactivating device 
(reason 'user-requested') [39]
May 23 22:43:22 jsm pppd[2335]: Terminating on signal 15
May 23 22:43:22 jsm pppd[2335]: Connect time 33.5 minutes.
May 23 22:43:22 jsm pppd[2335]: Sent 816683 bytes, received 23488634 bytes.
May 23 22:43:22 jsm NetworkManager[666]: nm_system_iface_flush_routes: 
assertion `ifindex > 0' failed
May 23 22:43:22 jsm NetworkManager[666]: nm_system_iface_flush_addresses: 
assertion `ifindex > 0' failed
May 23 22:43:22 jsm pppd[2335]: Connection terminated.
May 23 22:43:22 jsm avahi-daemon[663]: Withdrawing workstation service for ppp0.
May 23 22:43:22 jsm dnsmasq[2388]: exiting on receipt of SIGTERM
May 23 22:43:22 jsm NetworkManager[666]: <info> DNS: starting dnsmasq...
May 23 22:43:22 jsm NetworkManager[666]: <info> (ttyACM0): writing resolv.conf 
to /sbin/resolvconf
May 23 22:43:23 jsm dnsmasq[3230]: started, version 2.59 cache disabled
May 23 22:43:23 jsm dnsmasq[3230]: compile time options: IPv6 GNU-getopt DBus 
i18n DHCP TFTP conntrack IDN
May 23 22:43:23 jsm dnsmasq[3230]: warning: no upstream servers configured
May 23 22:43:23 jsm modem-manager[642]: <info>  Modem 
/org/freedesktop/ModemManager/Modems/0: state changed (connected -> 
disconnecting)
May 23 22:43:23 jsm dbus[508]: [system] Activating service 
name='org.freedesktop.nm_dispatcher' (using servicehelper)
May 23 22:43:23 jsm NetworkManager[666]:    SCPlugin-Ifupdown: devices removed 
(path: /sys/devices/virtual/net/ppp0, iface: ppp0)
May 23 22:43:23 jsm dbus[508]: [system] Successfully activated service 
'org.freedesktop.nm_dispatcher'
May 23 22:43:24 jsm modem-manager[642]: <info>  Modem 
/org/freedesktop/ModemManager/Modems/0: state changed (disconnecting -> 
registered)
May 23 22:43:27 jsm modem-manager[642]: <info>  (ttyACM0) closing serial port...
May 23 22:43:27 jsm modem-manager[642]: <info>  (ttyACM0) serial port closed
May 23 22:43:27 jsm kernel: [ 2975.160088] usb 3-1: USB disconnect, device 
number 2
May 23 22:43:27 jsm modem-manager[642]: <info>  (tty/ttyACM0): released by 
modem /sys/devices/pci0000:00/0000:00:1a.0/usb3/3-1
May 23 22:43:27 jsm modem-manager[642]: <info>  Modem 
/org/freedesktop/ModemManager/Modems/0: state changed (registered -> disabled)
May 23 22:43:27 jsm NetworkManager[666]: <info> (ttyACM0): now unmanaged
May 23 22:43:27 jsm NetworkManager[666]: <info> (ttyACM0): device state change: 
disconnected -> unmanaged (reason 'removed') [30 10 36]
May 23 22:43:27 jsm NetworkManager[666]: <info> (ttyACM0): cleaning up...
May 23 22:43:27 jsm NetworkManager[666]: <info> (ttyACM0): taking down device.
May 23 22:43:27 jsm NetworkManager[666]: <info> Unmanaged Device found; state 
CONNECTED forced. (see http://bugs.launchpad.net/bugs/191889)
May 23 22:43:27 jsm NetworkManager[666]: <info> Unmanaged Device found; state 
CONNECTED forced. (see http://bugs.launchpad.net/bugs/191889)
May 23 22:43:36 jsm kernel: Kernel logging (proc) stopped.
May 23 22:43:36 jsm rsyslogd: [origin software="rsyslogd" swVersion="5.8.6" 
x-pid="504" x-info="http://www.rsyslog.com";] exiting on signal 15.

And my machine configuration is
Processor - Intel® Core™2 Duo CPU E4600 @ 2.40GHz × 2 
OS type    - 64Bit
Memory   - 2GB

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https://bugs.launchpad.net/bugs/191889

Title:
  [MASTER] [WORKAROUND] "Offline Mode" feature fails to detect proper
  online state for networks that are managed outside of network manager.

Status in The Mozilla Firefox Browser:
  Fix Released
Status in NetworkManager:
  New
Status in ntrack - Network Connectivity Tracking library for Desktop 
Applications:
  Incomplete
Status in USB ADSL Modem Manager for Gnome, written in Python:
  New
Status in “empathy” package in Ubuntu:
  Fix Released
Status in “evolution” package in Ubuntu:
  Invalid
Status in “firefox-3.0” package in Ubuntu:
  Invalid
Status in “network-manager” package in Ubuntu:
  Incomplete
Status in “network-manager-applet” package in Ubuntu:
  Fix Released
Status in “pidgin” package in Ubuntu:
  Fix Released
Status in “empathy” source package in Hardy:
  Invalid
Status in “evolution” source package in Hardy:
  Invalid
Status in “firefox-3.0” source package in Hardy:
  Invalid
Status in “network-manager” source package in Hardy:
  Invalid
Status in “network-manager-applet” source package in Hardy:
  Incomplete
Status in “pidgin” source package in Hardy:
  Invalid
Status in “empathy” source package in Intrepid:
  Fix Released
Status in “evolution” source package in Intrepid:
  Invalid
Status in “firefox-3.0” source package in Intrepid:
  Invalid
Status in “network-manager” source package in Intrepid:
  Won't Fix
Status in “network-manager-applet” source package in Intrepid:
  Fix Released
Status in “pidgin” source package in Intrepid:
  Fix Released
Status in Baltix GNU/Linux:
  Fix Released

Bug description:
  Binary package hint: firefox-3.0

  DISTRIB_ID=Ubuntu
  DISTRIB_RELEASE=8.04
  DISTRIB_CODENAME=hardy
  DISTRIB_DESCRIPTION="Ubuntu hardy (development branch)"
  Firefox 3.0b3
  When I start firefox from the panel it always start in offline mode. I am 
connected via wireless to a network that is always on. When I want to browse I 
need to unclick "work offline"

  Workaround 1: (since ffox 3.0.1) ->
   set toolkit.networkmanager.disable to false in about:config

  Workaround 2: (make NM to be always online) ->
   add a non existing interface to /etc/network/interfaces, like:

  iface eth1000 inet dhcp

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