I had the same problem.

It seems that when I choose a color in the control panel it writes something 
like:
rgb(78,154,6) in the primary color field of the scheme 
org.gnome.desktop.background

Changing this by any hexdecimal number fix the problem.

It is worth to be mentionned that I installed the gnome3 ppa before
removing it with the ppa-purge command. I don't know if the problem was
present before this or not.

Hope that help,
nbl

-- 
You received this bug notification because you are a member of Desktop
Packages, which is subscribed to gnome-control-center in Ubuntu.
https://bugs.launchpad.net/bugs/1173818

Title:
  Unable to set solid colors and gradients as desktop background in
  gnome-control-center

Status in “gnome-control-center” package in Ubuntu:
  Confirmed

Bug description:
  Only black background  is coming

  ProblemType: Bug
  DistroRelease: Ubuntu 13.04
  Package: gnome-control-center 1:3.6.3-0ubuntu24
  ProcVersionSignature: Ubuntu 3.8.0-19.29-generic 3.8.8
  Uname: Linux 3.8.0-19-generic x86_64
  ApportVersion: 2.9.2-0ubuntu8
  Architecture: amd64
  Date: Sun Apr 28 06:35:00 2013
  ExecutablePath: /usr/bin/gnome-control-center
  InstallationDate: Installed on 2013-02-12 (74 days ago)
  InstallationMedia: Ubuntu 12.10 "Quantal Quetzal" - Release amd64 (20121017.5)
  MarkForUpload: True
  SourcePackage: gnome-control-center
  UpgradeStatus: Upgraded to raring on 2013-04-26 (1 days ago)
  XsessionErrors:
   (nautilus:1696): GLib-GObject-CRITICAL **: g_object_set: assertion 
`G_IS_OBJECT (object)' failed
   (nautilus:1696): GLib-GObject-CRITICAL **: g_object_set: assertion 
`G_IS_OBJECT (object)' failed
   (gnome-control-center:2169): gnome-control-center-unity-WARNING **: Could 
not load /usr/share/themes/Adwaita/index.theme: No such file or directory
   (gnome-control-center:2169): gnome-control-center-unity-WARNING **: Could 
not load /usr/share/themes/Adwaita/index.theme: No such file or directory
  usr_lib_gnome-control-center:
   activity-log-manager-control-center 0.9.4-0ubuntu6.1
   deja-dup                            26.0-0ubuntu1
   gnome-control-center-signon         0.1.6bzr13.04.05-0ubuntu1
   gnome-control-center-unity          1.2daily13.04.09-0ubuntu1
   indicator-datetime                  12.10.3daily13.03.26-0ubuntu1

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