i've encountered similar problem + a special bonus : couldn't change 
preferences.
launching empathy in a terminal to get the error message reported that 
.config/dconf/user could not be written

mkdr .config/dconf solved the issue !

hope it'll help.

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You received this bug notification because you are a member of Desktop
Packages, which is subscribed to empathy in Ubuntu.
https://bugs.launchpad.net/bugs/838697

Title:
  "Ubuntu" theme not applied to chat

Status in “empathy” package in Ubuntu:
  Confirmed

Bug description:
  When firing up Empathy for the first time in 11.10, the Ubuntu chat
  theme was not applied. Everything looked pretty ugly. When I went to
  the settings window and reselected it, it worked again. Pretty bad
  impression for first time users.

  ProblemType: Bug
  DistroRelease: Ubuntu 11.10
  Package: empathy 3.1.5.1-1ubuntu2
  ProcVersionSignature: Ubuntu 3.0.0-9.15-generic 3.0.3
  Uname: Linux 3.0.0-9-generic x86_64
  NonfreeKernelModules: nvidia
  Architecture: amd64
  CheckboxSubmission: f3d213e5470c375b2086fc25bce53912
  CheckboxSystem: b845c366ea09c60efa3a45c1b5b21525
  Date: Thu Sep  1 12:08:31 2011
  InstallationMedia: Ubuntu 11.10 "Oneiric Ocelot" - Alpha amd64 (20110824)
  SourcePackage: empathy
  UpgradeStatus: No upgrade log present (probably fresh install)

To manage notifications about this bug go to:
https://bugs.launchpad.net/ubuntu/+source/empathy/+bug/838697/+subscriptions

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