"Can anyone recommend a safe polish or other to aid in buffing out a minor 
surface scratch on the plastic (Perspex/acrylic?) screen cover"

Meguiar's Mirror Glaze MGH-17.

I have used it on aircraft and other transparencies.  Deep scratches may 
require work with increasingly fine abrasives.  MGH-17 will remove the marks 
left by 1200 grit.

73,
Andy, k3wyc
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