Mike. You are right.
I forgot to see with the hosts_require_tls enabled for this host.
So... There are a strange behavior...
I have the correct user, the correct password and try again using the TLS.
And... On debug log... I had the same auth fail problem:

  SMTP>> STARTTLSwaiting for data on socketread response data: size=29  SMTP<< 
220 2.0.0 SMTP server readysetting SSL CTX options: 0x1000000Diffie-Hellman 
initialized from default with 2048-bit primeInitialized TLSCalling 
SSL_connectSSL info: before/connect initializationSSL info: before/connect 
initializationSSL info: SSLv2/v3 write client hello ASSL info: SSLv3 read 
server hello ASSL info: SSLv3 read server certificate ASSL info: SSLv3 read 
server done ASSL info: SSLv3 write client key exchange ASSL info: SSLv3 write 
change cipher spec ASSL info: SSLv3 write finished ASSL info: SSLv3 flush 
dataSSL info: SSLv3 read finished ASSL info: SSL negotiation finished 
successfullySSL info: SSL negotiation finished successfullySSL_connect 
succeededCipher: TLSv1:AES128-SHA:128  SMTP>> EHLO 
host.mylocalsmtp.com.brtls_do_write(0xbf9ff3fc, 25)SSL_write(SSL, 0xbf9ff3fc, 
25)outbytes=25 error=0waiting for data on socketCalling SSL_read(0x8143148, 
0xbf9fd3fc, 4096)read response data: size=176  SMTP<<
  250-pod51028.outlook.com Hello [189.74.52.32]         250-SIZE 36700160       
  250-PIPELINING         250-DSN         250-ENHANCEDSTATUSCODES         
250-AUTH LOGIN         250-8BITMIME         250-BINARYMIME         250 
CHUNKING207.46.4.237 in hosts_avoid_pipelining? no (option unset)using 
PIPELININGgethostbyname looked up these IP addresses:  
name=pod51028.outlook.com address=207.46.4.237207.46.4.237 in 
hosts_require_auth? yes (matched "pod51028.outlook.com")scanning authentication 
mechanismsskipping server_plain authenticator: not configured as a 
clientskipping server_login authenticator: not configured as a client  SMTP>> 
AUTH LOGINtls_do_write(0xbf9ff3fc, 12)SSL_write(SSL, 0xbf9ff3fc, 12)outbytes=12 
error=0waiting for data on socketCalling SSL_read(0x8143148, 0xbf9fd3fc, 
4096)read response data: size=18  SMTP<< 334 VXNlcm5hbWU6search_open: lsearch 
"/opt/addons/etc/exim/client_credentials.conf"search_find: 
file="/opt/addons/etc/exim/client_credentials.conf"  key="emexis_redire
 ct_delivery_5" partial=-1 affix=NULL starflags=0LRU list:  
5/opt/addons/etc/exim/client_credentials.conf  Endinternal_search_find: 
file="/opt/addons/etc/exim/client_credentials.conf"  type=lsearch 
key="redirect_delivery_5"file lookup required for redirect_delivery_5  in 
/opt/addons/etc/exim/client_credentials.conflookup yielded: user="xxx@domain" 
pass="mypass"  SMTP>> ****************************tls_do_write(0xbf9ff3fc, 
30)SSL_write(SSL, 0xbf9ff3fc, 30)outbytes=30 error=0waiting for data on 
socketCalling SSL_read(0x8143148, 0xbf9fd3fc, 4096)read response data: size=18  
SMTP<< 334 UGFzc3dvcmQ6search_open: lsearch 
"/opt/addons/etc/exim/client_credentials.conf"  cached opensearch_find: 
file="/opt/addons/etc/exim/client_credentials.conf"  
key="emexis_redirect_delivery_5" partial=-1 affix=NULL starflags=0LRU list:  
5/opt/addons/etc/exim/client_credentials.conf  Endinternal_search_find: 
file="/opt/addons/etc/exim/brc_client_credentials.conf"  type=lsearch 
key="redirect_delivery_5"cached d
 ata used for lookup of redirect_delivery_5  in 
/opt/addons/etc/exim/client_credentials.conflookup yielded: user="xxx@domain" 
pass="mypass"  SMTP>> ************tls_do_write(0xbf9ff3fc, 14)SSL_write(SSL, 
0xbf9ff3fc, 14)outbytes=14 error=0waiting for data on socketCalling 
SSL_read(0x8143148, 0xbf9fd3fc, 4096)read response data: size=39  SMTP<< 535 
5.7.3 Authentication unsuccessful


                                          
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