Could you test again with -qmin 1 -qscale 1 ?  

I tested again with those settings, and the result is better, but still not as 
good as a conversion by OS X Preview.  I’m only observing visually, using 
Preview.app.  The blockiness is especially noticeable on the black shirt chest 
area.  Here are example files. The one created by FFmpeg with qmin 1 is 609KB.  
The one created by Preview is 1.9MB, and is nearly identical to the TIFF.

Original TIFF: 
https://drive.google.com/file/d/0B52QuT8oHvtZZkhSUkswUDhJSlU/view?usp=sharing
Preview: 
https://drive.google.com/file/d/0B52QuT8oHvtZYU5MX0dJWjcxdkU/view?usp=sharing
FFmpeg: 
https://drive.google.com/file/d/0B52QuT8oHvtZRW9SZjhsU2pYakE/view?usp=sharing
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