Hi David,

Following up on Mauna Loa data, there was a low mean reading for July which was 
subsequently corrected, because only the last 10 days of the month had actual 
readings from which the average had originally been calculated.  See:
http://tamino.wordpress.com/2008/08/05/revising-mauna-loa-co2-monthly-data/

Nevertheless the trend this year has been below expectation.  The reason could 
well be the Pacific cooling from La Nina - cooler water allowing greater 
absorption of CO2. See
http://wattsupwiththat.com/2008/04/06/co2-monthly-mean-at-mauna-loa-leveling-off/

What is really scary is that the next few years could bring an El Nino plus 
extra solar activity - a double whammy on global warming and the melting of the 
Arctic sea ice.  This makes the saving of the Arctic sea ice even more urgent.

Cheers,

John


  ----- Original Message ----- 
  From: David Schnare 
  To: [email protected] 
  Sent: Sunday, November 23, 2008 8:25 PM
  Subject: [geo] Re: Carbon is forever (Nature online news story)


  Ken:

  I have followed the carbon cycle literature and agree with Mike's basic 
statement that as we pull carbon out of "deep sinks" and inject it back into 
the dynamic cycle, we can't help but see some increases in atmospheric carbon.  

  The point I make is much more simple - the Mona Loa data is showing a slower 
rate of increase than we have seen in the past, and this does not correlate 
with the increasing rate of carbon injection into the dynamic cycle.  The 
"consensus" does not account for this hard data.  

  Indeed, I'm not sure what "consensus" means anymore.  Clearly, it ought to 
reflect the best data we have, and the modeling of the cycle does not seem to 
match the data, hence my disquiet.  

  David.


  On Sun, Nov 23, 2008 at 11:05 AM, Ken Caldeira <[EMAIL PROTECTED]> wrote:

    That lack of confidence is unjustified. There is general consensus among 
those who have studied the carbon cycle.

    The problem is confusion and not lack of knowledge.

    The main confusion comes from the fact that we can be talking about two 
very different things, for example:

    (1) What is the residence time of a particular CO2 molecule in the 
atmosphere? The answer to this question is in the range mentioned by David 
Schnare.

    (2) How long does it take for a perturbation in concentration to return to 
steady-state? The answer to this question is the one addressed by Mason Inman 
and the articles he discusses.

    At steady-state, CO2 in the atmosphere is exchanging CO2 with the ocean 
surface and the living biosphere. The large fluxes into these two reservoirs 
are compensated by large fluxes in the opposite direction. At steady state, 
molecules are still exchanging but there is no concentration perturbation that 
is decaying away.

    The other main source of confusion is that CO2 concentration perturbations 
do not decay away according to a simple exponentially decreasing function, so 
there is no single lifetime that can be referred to without reference to a 
specific definition of how lifetime is being used in that context.

    The last main source of confusion is that the decay of a CO2 concentration 
perturbation depends in part on the assumed background scenario. CO2 
disappeared more rapidly from the atmosphere 200 years ago than it does today.

    On top of all of this, there is basic process uncertainty. However, this 
process uncertainty is not so large as to place the general shape of the curve 
in significant doubt. Scientists are arguing about the details and not the 
basic picture, so David Schnare's lack of confidence is misplaced. I note that 
even though the Matthews and Caldeira paper appeared in Geophysical Research 
Letters early this year, there has been no scientific criticism of the 
conclusions in the literature -- indicating that there is a general consensus 
among informed scientists.

    The largest carbon cycle uncertain remains the fate of the biosphere (will 
it gain or lose carbon, how much, when?). However, the biosphere contains much 
less carbon than are contained in fossil fuel resources, so the biosphere 
[absent engineering of the biosphere] cannot play a first order role if we do 
end up transferring all of this CO2 to the atmosphere.

    Best,

    Ken 



    On Sun, Nov 23, 2008 at 6:31 AM, David Schnare <[EMAIL PROTECTED]> wrote:

      Ken, John, et al:

      My confidence in our understanding of the carbon cycle has reached what I 
hope is a nadir.  Attached is a chart of Mona Loa CO2 data and actual CO2 
emissions data.  They do not reflect a 100 year dwell time in the atmosphere.  
The literature on CO2 half-life suggests a 7.5 year half-life with the range 
from about 5 to 15 years.  That range is a better explanation of the actual CO2 
data than the modeled estimates (by a wide margin).  

      Thus, one wonders, what are the GCM modelers assuming, and how close to 
reality is that?

      David Schnare
      Center for Environmental Stewardship


       
      On Sun, Nov 23, 2008 at 6:03 AM, John Nissen <[EMAIL PROTECTED]> wrote:


        Hi Ken,

        You are forgiven for breaking the rules, because you are not.  What you 
have posted is extremely relevent - and is what started me off on taking 
geoengineering seriously - not the carbon capture but the aerosol cooling 
geoengineering.   We need to understand the carbon cycle in order to appreciate 
the imperative for geoengineered cooling.

        There is no alternative to geoengineered cooling in the short term, the 
awsome problem of saving the Arctic sea ice - which is ignored in this article. 
 I know you appreciate this [1].

        When I read the IPCC report in 2007 about stabilisation at 2 degrees, I 
could not understand how they arrived at the "climate sensitivity", on which 
all their calculations seemed to be based.  When I looked into it, their 
calculations seemed to use 140 years as the lifetime for CO2 - the half life 
for the 50% of CO2 which is not immediately absorbed.  
        Your article does not explain that, as CO2 concentration increases in 
the atmosphere, the equilibrium concentration in the ocean and biomass 
increases.  This explains the almost exactly 50% of CO2 which is immediately 
absorbed.

        It is the lifetime of the remaining 50% which is of concern.  If we 
halted all CO2 emissions overnight, what would the effect be?   IPCC gave a 
mean estimate of around 140 years.  Yet I found papers saying that this 
lifetime was thousands of years - one gave 32,000 years as an estimate.  Who 
was right?  I suspected the longer time could be correct, and your research 
confirms that.  So emissions reduction, however severe, would not halt global 
warming.

        Your article suggests the answer is geoengineering to remove carbon.  
But we do not have the time.  We have to apply cooling techniques, of which 
only the stratospheric aerosols and marine cloud brightening techniques offer 
high feasibility of sufficient scaleability over the few seasons to save the 
Arctic sea ice from disappearing over the next few years.

        Thus your article is highly relevent to geoengineering.

        Cheers from Chiswick,

        John


        [1] You gave a telling postscript to a recent posting of yours (re 
Worldwatch Book):

        PS. By the way, given that changes in CO2 emissions will not 
significantly affect temperatures over the next decade or two in any plausible 
scenario, it is hard to image how anything other than climate engineering can 
significantly reduce climate risk over this time period (perhaps there are 
adaptive strategies that could reduce this risk, but it is hard to see how 
those would apply to sea ice, ice sheets, arctic ecosystems, and permafrost).


          ----- Original Message ----- 
          From: Ken Caldeira 
          To: geoengineering 
          Sent: Saturday, November 22, 2008 3:08 AM
          Subject: [geo] Carbon is forever (Nature online news story)


          NOTE: I AM BREAKING THE RULE ABOUT POSTING GENERAL CLIMATE/CARBON 
POSTS TO THIS GROUP. (BAD, BAD, BAD)




          http://www.nature.com/climate/2008/0812/full/climate.2008.122.html 



          News Feature
          Nature Reports Climate Change 
          Published online: 20 November 2008 | doi:10.1038/climate.2008.122

          Carbon is forever
          Carbon dioxide emissions and their associated warming could linger 
for millennia, according to some climate scientists. Mason Inman looks at why 
the fallout from burning fossil fuels could last far longer than expected.

           
          Distant future: our continued use of fossil fuels could leave a 
CO2legacy that lasts millennia, says climatologist David Archer

          123RF.COM/PAUL MOORE

          After our fossil fuel blow-out, how long will the CO2 hangover last? 
And what about the global fever that comes along with it? These sound like 
simple questions, but the answers are complex — and not well understood or 
appreciated outside a small group of climate scientists. Popular books on 
climate change — even those written by scientists — if they mention the 
lifetime of CO2 at all, typically say it lasts "a century or more"1 or "more 
than a hundred years".

          "That's complete nonsense," says Ken Caldeira of the Carnegie 
Institution for Science in Stanford, California. It doesn't help that the 
summaries in the Intergovernmental Panel on Climate Change (IPCC) reports have 
confused the issue, allege Caldeira and colleagues in an upcoming paper in 
Annual Reviews of Earth and Planetary Sciences2. Now he and a few other climate 
scientists are trying to spread the word that human-generated CO2, and the 
warming it brings, will linger far into the future — unless we take heroic 
measures to pull the gas out of the air.

          University of Chicago oceanographer David Archer, who led the study 
with Caldeira and others, is credited with doing more than anyone to show how 
long CO2 from fossil fuels will last in the atmosphere. As he puts it in his 
new book The Long Thaw, "The lifetime of fossil fuel CO2 in the atmosphere is a 
few centuries, plus 25 percent that lasts essentially forever. The next time 
you fill your tank, reflect upon this"3.

          "The climatic impacts of releasing fossil fuel CO2 to the atmosphere 
will last longer than Stonehenge," Archer writes. "Longer than time capsules, 
longer than nuclear waste, far longer than the age of human civilization so 
far."

          The effects of carbon dioxide on the atmosphere drop off so slowly 
that unless we kick our "fossil fuel addiction", to use George W. Bush's 
phrase, we could force Earth out of its regular pattern of freezes and thaws 
that has lasted for more than a million years. "If the entire coal reserves 
were used," Archer writes, "then glaciation could be delayed for half a million 
years."

          Cloudy reports
          "The longevity of CO2 in the atmosphere is probably the least well 
understood part of the global warming issue," says paleoclimatologist Peter 
Fawcett of the University of New Mexico. "And it's not because it isn't well 
documented in the IPCC report. It is, but it is buried under a lot of other 
material."

          It doesn't help, though, that past reports from the UN panel of 
climate experts have made misleading statements about the lifetime of CO2, 
argue Archer, Caldeira and colleagues. The first assessment report, in 1990, 
said that CO2's lifetime is 50 to 200 years. The reports in 1995 and 2001 
revised this down to 5 to 200 years. Because the oceans suck up huge amounts of 
the gas each year, the average CO2 molecule does spend about 5 years in the 
atmosphere. But the oceans also release much of that CO2 back to the air, such 
that man-made emissions keep the atmosphere's CO2 levels elevated for 
millennia. Even as CO2 levels drop, temperatures take longer to fall, according 
to recent studies.

          "The climatic impacts of releasing fossil fuel CO2 to the atmosphere 
will last longer than Stonehenge, longer than time capsules, longer than 
nuclear waste, far longer than the age of human civilization so far."

          David Archer

          Earlier reports from the panel did include caveats such as "No single 
lifetime can be defined for CO2 because of the different rates of uptake by 
different removal processes." The IPCC's latest assessment, however, avoids the 
problems of earlier reports by including similar caveats while simply refusing 
to give a numeric estimate of the lifetime for carbon dioxide. Contributing 
author Richard Betts of the UK Met Office Hadley Centre says the panel made 
this change in recognition of the fact that "the lifetime estimates cited in 
previous reports had been potentially misleading, or at least open to 
misinterpretation."

          Instead of pinning an absolute value on the atmospheric lifetime of 
CO2, the 2007 report describes its gradual dissipation over time, saying, 
"About 50% of a CO2 increase will be removed from the atmosphere within 30 
years, and a further 30% will be removed within a few centuries. The remaining 
20% may stay in the atmosphere for many thousands of years." But if cumulative 
emissions are high, the portion remaining in the atmosphere could be higher 
than this, models suggest. Overall, Caldeira argues, "the whole issue of our 
long-term commitment to climate change has not really ever been adequately 
addressed by the IPCC."

          The lasting effects of CO2 also have big implications for energy 
policies, argues James Hansen, director of NASA's Goddard Institute of Space 
Studies. "Because of this long CO2 lifetime, we cannot solve the climate 
problem by slowing down emissions by 20% or 50% or even 80%. It does not matter 
much whether the CO2 is emitted this year, next year, or several years from 
now," he wrote in a letter this August. "Instead ... we must identify a portion 
of the fossil fuels that will be left in the ground, or captured upon emission 
and put back into the ground."

          Slow on the uptake
          Unlike other human-generated greenhouse gases, CO2 gets taken up by a 
variety of different processes, some fast and some slow. This is what makes it 
so hard to pin a single number, or even a range, on CO2's lifetime. The 
majority of the CO2 we emit will be soaked up by the ocean over a few hundred 
years, first being absorbed into the surface waters, and eventually into deeper 
waters, according to a long-term climate model run by Archer. Though the ocean 
is vast, the surface waters can absorb only so much CO2, and currents have to 
bring up fresh water from the deep before the ocean can swallow more. Then, on 
a much longer timescale of several thousand years, most of the remaining CO2 
gets taken up as the gas dissolves into the ocean and reacts with chalk in 
ocean sediments. But this process would never soak up enough CO2 to return 
atmospheric levels to what they were before industrialization, shows 
oceanographer Toby Tyrrell of the UK's National Oceanography Centre, 
Southampton, in a recent paper4.

          Finally, the slowest process of all is rock weathering, during which 
atmospheric CO2 reacts with water to form a weak acid that dissolves rocks. 
It's thought that this creates minerals such as magnesium carbonate that lock 
away the greenhouse gas. But according to simulations by Archer and others, it 
would take hundreds of thousands of years for these processes to bring CO2 
levels back to pre-industrial values (Fig. 1).

          Figure 1: Long lifetime.
           
          Model simulation of atmospheric CO2 concentration for 40,000 years 
following after a large CO2 release from combustion of fossil fuels. Different 
fractions of the released gas recover on different timescales. Reproduced from 
The Long Thaw3.

          Full figure and legend (18 KB) 



          Several long-term climate models, though their details differ, all 
agree that anthropogenic CO2 takes an enormously long time to dissipate. If all 
recoverable fossil fuels were burnt up using today's technologies, after 1,000 
years the air would still hold around a third to a half of the CO2 emissions. 
"For practical purposes, 500 to 1000 years is 'forever,'" as Hansen and 
colleagues put it. In this time, civilizations can rise and fall, and the 
Greenland and West Antarctic ice sheets could melt substantially, raising sea 
levels enough to transform the face of the planet.

          New stable state
          The warming from our CO2 emissions would last effectively forever, 
too. A recent study by Caldeira and Damon Matthews of Concordia University in 
Montreal found that regardless of how much fossil fuel we burn, once we stop, 
within a few decades the planet will settle at a new, higher temperature5. As 
Caldeira explains, "It just increases for a few decades and then stays there" 
for at least 500 years — the length of time they ran their model. "That was not 
at all the result I was expecting," he says.

          But this was not some peculiarity of their model, as the same 
behaviour shows up in an extremely simplified model of the climate6 — the only 
difference between the models being the final temperature of the planet. Archer 
and Victor Brovkin of the Potsdam Institute for Climate Impact Research in 
Germany found much the same result from much longer-term simulations6. Their 
model shows that whether we emit a lot or a little bit of CO2, temperatures 
will quickly rise and plateau, dropping by only about 1 °C over 12,000 years.

          "The longevity of CO2 in the atmosphere is probably the least well 
understood part of the global warming issue."

          Peter Fawcett

          Because of changes in the Earth's orbit, ice sheets might start to 
grow from the poles in a few thousand years — but there's a good chance our 
greenhouse gas emissions already may prevent that, Archer argues. Even with the 
amount of CO2 emitted so far, another ice age will almost certainly start in 
about 50,000 years. But if we burn all remaining fossil fuels, it could be more 
than half a million years before the Earth has another ice age, Archer says.

          The long-term effects of our emissions might seem far removed. But as 
Tyrrell says, "It is a little bit scary, if you think about all the concerns we 
have about radioactive wastes produced by nuclear power. The potential impacts 
from emitting CO2 to the atmosphere are even longer than that." But there's 
still hope for avoiding these long-term effects if technologies that are now on 
the drawing board can be scaled up affordably. "If civilization was able to 
develop ways of scrubbing CO2 out of the atmosphere," Tyrrell says, "it's 
possible you could reverse this CO2 hangover."

          Top of page 
          References
            1.. Flannery, T. The Weather Makers: The History and Future Impact 
of Climate Change 162 (Atlantic Monthly Press, New York, 2005). 
            2.. Archer, D. et al. Ann. Rev. Earth Pl. Sc. (in the press). 
            3.. Archer, D. The Long Thaw: How Humans Are Changing the Next 
100,000 Years of Earth's Climate (Princeton Univ. Press, 2008). 
            4.. Tyrrell, T., Shepherd, J. G. & Castle, S. Tellus 59, 664–672, 
doi:10.1111/j.1600-0889.2007.00290.x (2007). 
            5.. Matthews, H. D. & Caldeira, K. Geophys. Res. Lett. 35, L04705, 
doi:10.1029/2007GL032388 (2008). 
            6.. Archer, D. & Brovkin, V. Climatic Change 90, 283–297 (2008).
          Mason Inman is a freelance science writer currently based in Pakistan.



          Ken Caldeira
          Department of Global Ecology
          Carnegie Institution
          260 Panama Street 
          Stanford, CA 94305 USA
          +1 650 704 7212; fax: +1 650 462 5968

          [EMAIL PROTECTED]
          [EMAIL PROTECTED]

          http://dge.stanford.edu/DGE/CIWDGE/labs/caldeiralab/




          Center for Environmental Stewardship

          

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