Dear all,

In case you were not aware, the workshop, which was to have been 3-4th
September, is now going to be on 15-16th October.  Here is the background
and purpose of the workshop.

A group of scientists and engineers (including myself) is deeply concerned
about the potential of methane from thawing permafrost in the Arctic to
cause runaway global warming.   Major factors are the unexpectedly rapid
retreat of sea ice [1] and the unexpectedly large quantities of carbon which
might be emitted as methane [2].  In June 2010 we wrote an open letter to
Obama's scientific adviser, Dr John Holdren, suggesting action was urgently
needed to address the methane issue [3].   Some sea ice experts, including
Professor Peter Wadhams in our group, now reckon the Arctic ocean will very
likely become seasonably ice free this decade if there is no action to cool
the Arctic.

Recently Peter Wadhams has drawn my attention to work of Natalia Shakhova
with Igor Semiletov on East Siberian Arctic Shelf (ESAS) - particularly
concerning the present large emissions of methane and the possibility of
release of much larger quantities "at any time".   So we have been wondering
whether anything can be done quickly to reduce this methane threat.   We
have been discussing possible action, and plan further brainstorming at a
workshop in October in London.

We are hoping this workshop will lead on to a pilot project to trial the
most promising techniques.  Here is an extract from the proposal, concerning
management of the methane environment at the local level (e.g. in ESAS):

[begin quote]

Approaches can be categorised according to where the intervention action
takes place.  Where the methane is from lake or sea bed, the action could
be:


   - below the permafrost, where there may already be methane or methane
   hydrate;
   - in the permafrost, or to plug gaps in the permafrost where methane is
   rising;
   - in the bed of the sea or lake, above the permafrost layer;
   - in the water at the bottom of the sea or lake;
   - at the surface of the sea or lake, and below any ice;
   - at the point of emergence of methane into the atmosphere.


In the case of methane from wetlands, some of the above actions would be
relevant to ponds, commonly forming above permafrost and emitting most of
the wetlands methane.  There is also the possibility of pond drainage as a
means to reduce methane emissions.

Returning to the case of lakes and deeper water, the problem with trying to
deal with methane below the permafrost is that any disturbance is liable to
trigger an eruption of methane through gaps in permafrost known as
taliks.  Commercial
methods of extraction of natural gas can be used when there is in
impermeable layer above the gas, but cannot be applied in our situation
because of the danger either from puncture of the permafrost or from
enlarging existing taliks.

In the bed of the sea or lake there may be aerobic microbes, capable of
‘digesting’ the methane and converting it into less harmful products.  Supply
of oxygen and nutrients to such microbes could be helpful.  Microbes may
also congregate in a ‘biotic layer’ at the bottom of the sea or lake.  These
could be boosted or encouraged to proliferate.

Methane can dissolve in the water.  At atmospheric pressure and freezing
point, 0.04 grams of methane will dissolve in a litre of water.  Therefore
one approach could be to extract the water when it is nearly saturated with
methane.  A more commercial approach would be to use a specific methane
solvent in a relatively heavy layer, resting on the seabed (or lake
bed).   From
time to time the solvent would be extracted, scrubbed to remove the methane,
and replaced.  A major issue could be containing the solvent and making sure
there was no long-term harm to the marine habitat.

A general problem with emissions of soluble gas from the beds of lakes and
shallow seas is that the water column can become unstable – with the
dissolved gases coming out of solution, leading to a sometime violent
upwelling.  Because of the low density of the rising column of bubble-filled
water, ships on the surface can sink!   Furthermore any turnover of the
water allows warmer surface water to be transported towards the bottom,
which can lead to permafrost melt and enhanced methane production.  Thus any
underwater approach to methane must take into account the stability of the
water column.

However if the methane is already bubbling to the surface, then one could
consider capturing it before it escapes into the atmosphere.  One way would
be to use ice, which will anyway be present in winter.  The methane collects
under the ice, and boring through the ice, one could collect the methane
that emerges.  The problem would be keeping an intact layer of ice
throughout the year.  Therefore one might consider strengthening the ice to
produce ‘pykrete’ [3].   However a more promising approach would be to have
mats, preferably of methane-absorbing substance (biological or chemical)
which could be harvested to collect the methane.  But care would be needed
not to deplete oxygen from water underneath the mats, since oxygen is
required from the important methane-digesting microbes in any biotic layer
that has formed above the sea or lake bed.

If and when some methane bursts into the atmosphere, it could be burnt or
‘flared’.  In remote areas, and in open water, this could be
problematic.  Furthermore,
methane only burns in air at between 5% and 15% concentration by volume.  As
it disperses quickly, one would need to torch the methane within a few
seconds of eruption.  It is almost impossible to imagine how this could be
done in a remote location, unless the methane is laser-zapped from a
monitoring satellite!

[end quote]

The pilot project will promote a three-prong attack, though trials will
focus on local action (particular item 2):

1. cooling the Arctic, regionally or locally, using SRM geoengineering;
2. management of the methane environment at the local level (see quoted text
above);
3. capture or destruction of methane, already in the atmosphere.

The capture or destruction of methane in the atmosphere is a last resort, if
other approaches fail.  It would also be vital if there were a sudden large
emission of methane with serious warming potential.  Such "air capture" or
destruction could be local or not.  The advantage of local air capture is
that efficiency may be improved through having the methane at higher
concentration (as the efficiency is for CO2 air capture).

The workshop is intended as a brainstorming session to establish the most
promising techniques which might be trialled in the pilot project.   If you
have already expressed an interest in attending the workshop, please confirm
that the new date is OK.  If you have not yet expressed an interest, and
would like to attend, let me know.

John Nissen

Chiswick, London W4

[1] Copenhagen Diagnosis, 2009
http://www.ccrc.unsw.edu.au/Copenhagen/Copenhagen_Diagnosis_LOW.pdf
see figure 13 page 30.

[2] Ibid, see page 21 - referring to Shuur et al 2008.

[3]
http://geo-engineering.blogspot.com/2010/06/sea-ice-loss-stuns-scientists.html

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