http://pubs.rsc.org/en/Content/ArticleLanding/2012/EE/c2ee21586a

Air as the renewable carbon source of the future: an overview of CO2 capture 
from the atmosphere
Alain Goeppert ,  Miklos Czaun ,  G. K. Surya Prakash and George A. Olah
Energy Environ. Sci., 2012,5, 7833-7853
DOI: 10.1039/C2EE21586A
Received 09 Mar 2012, Accepted 01 May 2012


The burning of our diminishing fossil fuel reserves is accompanied by a large 
anthropogenic CO2 release, which is outpacing nature's CO2 recycling 
capability, causing significant environmental harm. Much is being done to avert 
this crisis including more efficient technology for usage, savings and 
replacing carbon fuels with alternatives whenever feasible. The capture of CO2 
followed by sequestration (CCS) into geologic formation or under the seas has 
also been proposed and in some cases implemented. Carbon capture and recycling 
(CCR) to fuels and materials is another promising approach. At first, capturing 
carbon dioxide from concentrated sources such as fossil fuel burning power 
plants, industrial plants and natural sources might be the most practical. 
However, the capture of CO2 from the atmosphere is also technically feasible 
despite its low concentration (390 ppm) and presents even some benefits 
compared to point source CO2 capture. The present article reviews methods 
developed for the capture of CO2 directly from the air as well as their 
advantages and drawbacks. While strong bases such as sodium hydroxide and 
potassium hydroxide could be used, their regeneration is energy intensive, 
requiring high temperatures. Amines either physically or chemically immobilized 
on solid supports require much lower temperatures for their regeneration and 
are therefore promising candidates.

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