Andrew,
 
Note that there have been proposals to displace the methane in hydrates 
with CO2 and thus store the CO2 as a hydrate  - here is an example: 

*http://www.pnas.org/content/103/34/12690.full*<http://www.pnas.org/content/103/34/12690.full>
Chris.

On Tuesday, 12 March 2013 11:10:09 UTC, andrewjlockley wrote:

> Posters note: this development is significant to geoengineering, as it 
> opens the way to extract methane from unstable clathrates, which may 
> otherwise be released into the atmosphere by global warming. However, it 
> also significantly increases the available stock of carbon fuels.
>
> http://www.bbc.co.uk/news/business-21752441
>
> Japan taps gas from methane hydrate
>
> Updated 24 minutes ago
>
> Japan says it has successfully extracted natural gas from frozen methane 
> hydrate off its central coast, in a world first.
>
> Methane hydrates, or clathrates, are a type of frozen "cage" of molecules 
> of methane and water.
>
> The gas field is about 50km away from Japan's main island, in the Nankai 
> Trough.
>
> Researchers say it could provide an alternative energy source for Japan 
> which imports all its energy needs.
>
> Other countries including Canada, the US and China have been looking into 
> ways of exploiting methane hydrate deposits as well.
>
> Pilot experiments in recent years, using methane hydrates found under land 
> ice, have shown that methane can be extracted from the deposits.
>
> Offshore deposits present a potentially enormous source of methane but 
> also some environmental concern, because the underwater geology containing 
> them is unstable in many places.
>
> "It is the world's first offshore experiment producing gas from methane 
> hydrate," an official from the economy, trade and industry ministry told 
> the AFP news agency.
>
> A survey of the gas field is being run by state-owned Japan Oil, Gas and 
> Metals National Corporation (JOGMEC).
>
> Engineers used a depressurisation method that turns methane hydrate into 
> methane gas.
>
> Production tests are expected to continue for about two weeks.
>
> Government officials have said that they aim to establish methane hydrate 
> production technologies for practical use within five years.
>
> A Japanese study estimated that at least 1.1tn cubic metres of methane 
> hydrate exist in offshore deposits.
>
> This is the equivalent of more than a decade of Japan's gas consumption.
>
> Japan has few natural resources and the cost of importing fuel has 
> increased after a backlash against nuclear power following the Fukushima 
> nuclear disaster two years ago.
>

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