Poster's note : previously discussed on the CDR list, where the
environmental impacts of diverting scrap metals to this use case were
discussed. A life cycle analysis would be helpful.

http://onlinelibrary.wiley.com/doi/10.1002/cssc.201702087/abstract

Capacitance-Assisted Sustainable Electrochemical Carbon Dioxide
Mineralisation
Authors

   - Dr. Katie J. Lamb,
   - <http://orcid.org/0000-0002-5244-5015>
   1.

   
<http://onlinelibrary.wiley.com/advanced/search/results?searchRowCriteria%5B0%5D.fieldName=author&start=1&resultsPerPage=20&searchRowCriteria%5B0%5D.queryString=%22Dr.%20Katie%20J.%20Lamb%22>
      -

      - Mark R. Dowsett,
   - <http://orcid.org/0000-0003-2313-416X>
   1.

   
<http://onlinelibrary.wiley.com/advanced/search/results?searchRowCriteria%5B0%5D.fieldName=author&start=1&resultsPerPage=20&searchRowCriteria%5B0%5D.queryString=%22Mark%20R.%20Dowsett%22>
      -

      - Dr. Konstantinos Chatzipanagis,
   1.

   
<http://onlinelibrary.wiley.com/advanced/search/results?searchRowCriteria%5B0%5D.fieldName=author&start=1&resultsPerPage=20&searchRowCriteria%5B0%5D.queryString=%22Dr.%20Konstantinos%20Chatzipanagis%22>
   - Dr. Zhan Wei Scullion,
   1.

   
<http://onlinelibrary.wiley.com/advanced/search/results?searchRowCriteria%5B0%5D.fieldName=author&start=1&resultsPerPage=20&searchRowCriteria%5B0%5D.queryString=%22Dr.%20Zhan%20Wei%20Scullion%22>
   - Dr. Roland Kröger,
   - <http://orcid.org/0000-0002-5070-0297>
   1.

   
<http://onlinelibrary.wiley.com/advanced/search/results?searchRowCriteria%5B0%5D.fieldName=author&start=1&resultsPerPage=20&searchRowCriteria%5B0%5D.queryString=%22Dr.%20Roland%20Kr%C3%B6ger%22>
   - Dr. James D. Lee,
   - <http://orcid.org/0000-0001-5397-2872>
   1.

   
<http://onlinelibrary.wiley.com/advanced/search/results?searchRowCriteria%5B0%5D.fieldName=author&start=1&resultsPerPage=20&searchRowCriteria%5B0%5D.queryString=%22Dr.%20James%20D.%20Lee%22>
   - Dr. Pedro M. Aguiar,
   - <pedro.agu...@umontreal.ca>
      - <http://orcid.org/0000-0003-2423-5536>
   1.
   -

   
<http://onlinelibrary.wiley.com/advanced/search/results?searchRowCriteria%5B0%5D.fieldName=author&start=1&resultsPerPage=20&searchRowCriteria%5B0%5D.queryString=%22Dr.%20Pedro%20M.%20Aguiar%22>
   - Prof. Michael North,
   - <michael.no...@york.ac.uk>
      - <http://orcid.org/0000-0002-6668-5503>
   1.
   -

   
<http://onlinelibrary.wiley.com/advanced/search/results?searchRowCriteria%5B0%5D.fieldName=author&start=1&resultsPerPage=20&searchRowCriteria%5B0%5D.queryString=%22Prof.%20Michael%20North%22>
   - Dr. Alison Parkin
   - <alison.par...@york.ac.uk>
      - <http://orcid.org/0000-0003-4715-7200>
   1.
   -

   
<http://onlinelibrary.wiley.com/advanced/search/results?searchRowCriteria%5B0%5D.fieldName=author&start=1&resultsPerPage=20&searchRowCriteria%5B0%5D.queryString=%22Dr.%20Alison%20Parkin%22>


   - First published:12 December 2017Full publication history
   
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   - DOI:10.1002/cssc.201702087  View/save citation
   
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   - Cited by (CrossRef):0 articlesCheck for updates
   
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   - Funding Information
   
<http://onlinelibrary.wiley.com/doi/10.1002/cssc.201702087/abstract#funding-information>

Abstract

An electrochemical cell comprising a novel dual-component graphite and
Earth-crust abundant metal anode, a hydrogen producing cathode and an
aqueous sodium chloride electrolyte was constructed and used for carbon
dioxide mineralisation. Under an atmosphere of 5 % carbon dioxide in
nitrogen, the cell exhibited both capacitive and oxidative electrochemistry
at the anode. The graphite acted as a supercapacitive reagent concentrator,
pumping carbon dioxide into aqueous solution as hydrogen carbonate.
Simultaneous oxidation of the anodic metal generated cations, which reacted
with the hydrogen carbonate to give mineralised carbon dioxide. Whilst
conventional electrochemical carbon dioxide reduction requires hydrogen,
this cell generates hydrogen at the cathode. Carbon capture can be achieved
in a highly sustainable manner using scrap metal within the anode, seawater
as the electrolyte, an industrially relevant gas stream and a solar panel
as an effective zero-carbon energy source.

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