See this thread for possible workarounds:
http://groups.google.com/group/google-appengine/browse_thread/thread/12d823a18bddd53b

On Dec 21, 6:07 am, Arun Shanker Prasad <arunshankerpra...@gmail.com>
wrote:
> Hi All,
>
>     I got the following error in my log when I tried to send an
> invitation mail to around 14 people,
>
> OverQuotaError: The API call mail.Send() required more quota than is
> available.
>
> I have read in the forums that during peak times only about 3-4 mails
> can be sent in a minute and pooling all this into one mail will also
> won't do the job also, as the number of people in the mails To lists
> will be considered individually....
>
> Is there anyway to get around this?? I am sending the mail as the site
> admin user, at least the admin user should be able to more mails in
> one request..
>
> Any suggestion or ideas?
>
> Thanks,
> Arun Shanker Prasad.
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