On 2/10/14, 11:31 AM, prasun kumar wrote:
Dear All and Justin

Thanx for the quick reply...
My aim is to find the effect of the ion on the dodecamer (whether on adding ions
it is stable or not)
Seeing the system.. I am left with two options (My view): 1) Coarse Grain Method
or 2. Implicit Solvent Method
Coarse Grain Method is full of approximation thats why I was hesitant to follow
this approach...

Well, implicit solvation is full of approximations, too.

According to you if not the implicit solvent method, then any suggestion you can
give..


Hard to say. I think there are some significant limitations of MD in general in this case. As I said before, the representation of a metal ion as a simple sphere with charge +2 is a fairly poor approximation. The MD force fields do not reproduce effects like charge transfer or maintain proper coordination geometry without complex restraints. If absolutely nothing else, I think you need to use an explicit solvent model.

-Justin

--
==================================================

Justin A. Lemkul, Ph.D.
Postdoctoral Fellow

Department of Pharmaceutical Sciences
School of Pharmacy
Health Sciences Facility II, Room 601
University of Maryland, Baltimore
20 Penn St.
Baltimore, MD 21201

[email protected] | (410) 706-7441
http://mackerell.umaryland.edu/~jalemkul

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