Hi all,
I think this comes from the misunderstanding of the effect and the try to explain it as the "additional" absorption of outgoing light. Am I right?
kicaj

W dniu 10-11-16 19:19, Scott Calvin pisze:
Hi all,

As some of you know, I'm currently working on a textbook on XAFS analysis. Because of that, I'm going to occasionally pose some questions for the list that may seem a bit random. I hope none of you mind me using the list in this way; the questions may seem to come out of left field, but I think they will still be of interest to many.

With that said, here's my question for today:

What is the origin of the use of "self-absorption" to describe the suppression of fine-structure observed in thick, concentrated samples measured in fluorescence? I understand the physics of the effect itself, my question is the curious wording. Compared to a thin concentrated sample, the effect might better be described as "saturation," while compared to a thick dilute sample, it's actually related to a lack of absorption by other elements.

--Scott Calvin
Faculty at Sarah Lawrence College
Currently on sabbatical at Stanford Synchrotron Radiation Laboratory
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