Here's the patent info for Vivian Albert's Solar Panel as reported @ KeelyNet 
today:

METHOD FOR THE PREPARATION OF GROUP IB-IIIA-VIA QUATERNARY OR HIGHER ALLOY 
SEMICONDUCTOR FILMS
Publication number:     CA2539556
Publication date:       2005-02-24
Inventor:       ALBERTS VIVIAN (ZA)
Applicant:      UNIV JOHANNESBURG (ZA)
Classification: 
- international:        H01L31/032; H01L31/18; H01L31/0264; H01L31/18;
- european:     H01L31/032C; H01L31/18
Application number:     CA20042539556 20040813
Priority number(s):     ZA20030006316 20030814; ZA20040002497 20040330; 
WO2004IB51458 20040813          
Also published as:
                WO2005017979 (A3)        
                WO2005017979 (A2)        
                WO2005017978 (A3)        
                WO2005017978 (A2)        
                EP1654769 (A3)
        
Abstract of CA2539556
This invention relates to a method for producing group IB-IIIA-VIA quaternar y 
or higher alloy semiconductor films wherein the method comprises the steps o f 
(i) providing a metal film comprising a mixture of group IB and group IIIA 
metals; (ii) heat treating the metal film in the presence of a source of a 
first group VIA element (said first group VIA element hereinafter being 
referred to as VIA1 ) under conditions to form a first film comprising a 
mixture of at least one binary alloy selected from the group consisting of a 
group IB -VIA1 alloy and a group IIIA~-VIA1 alloy and at least one group IB- 
IIIA-VIA1 ternary alloy (iii) optionally heat treating the first film in the 
presence of a source of a second group VIA element (said second group VI 
element hereinafter being referred to as VIA2) under conditions to convert t he 
first film into a second film comprising at least one alloy selected from th e 
group consisting of a group IB-VIA1-VIA2 alloy and a group IIIA-VIA1-VIA2 
alloy; and the at least one group IB-~III-VIA1 ternary alloy of step (ii); (iv) 
heat treating either the first film or second film to form a group IB- IIIA-VIA 
quaternary or higher alloy semiconductor film.

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