Hi St Augustine,

This issue could occur if you are sampling on 2 or more channels.  If
this is the case, you are probably seeing cross-talk (channel
ghosting) where voltages on previous channels are being seen on
subsequent channels in your sample list.  For example, if you have a
sinewave on the first channel and 5V on the second channel, you might
see remnants of each channel on the other, distorting your signal
slightly.  The best way to correct this is to increase the
interchannel delay.

Data Acquisition: Troubleshooting Unexpected Voltages or Cross-talk in
Analog Input Channels
http://digital.ni.com/public.nsf/websearch/B9BCDFD960C06B9186256A37007490CD?OpenDocument

If you are only sampling on one channel, you could check in
Measurement & Automation Explorer (MAX) to make sure that you are
seeing the same phenomenon being exhibited by the waveform.  In MAX,
you can right-click your PCI-6014 device and select Test Panels.  Then
you can adjust the sampling rate and watch the waveform directly from
the front end of the driver.

Another point is that it could still be that you are seeing
granularity because of the high frequency of your signal relative to
your sampling rate.  A sampling rate of 8x higher will still look much
more "squarish" then a sampling rate 100x faster.

Anyway, hope that helps.  Have a good day.

Ron

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