LabVIEW can communicate through the serial port using its VISA interface. LabVIEW comes with several example serial communication programs that should help you get started. Look in the Help menu and click "Find Examples...". After the dialog opens and gets populated, double click "Hardware Input and Output", then on "Serial" and there will be some samples you can start with.
As for actually talking to the camera, you'll have to get the serail command set from Kodak and build communications routines yourself, unless they, or somebody else already done that. Ed