Found it. There's a system-wide setting hidden under:

  System preferences > Keyboard > Text > "Use smart quotes and dashes"

-Carl

> On Jun 24, 2015, at 2:14 PM, Carl Hoefs <newsli...@autonomy.caltech.edu> 
> wrote:
> 
> Is there any way to tell Mail.app to stop using ‘smart’ quotes (‘’ and “”) in 
> plaintext emails? When I correspond with anyone using Windows, the quotes 
> become mangled in translation:
> 
>>    Did you say Œavailable now¹? If so, ...
>> 
> There is a setting in TextEdit for disabling smart quotes, but I don’t see 
> how to do it in Mail.
> -Carl
> 
> 

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