http://statter911.com/2013/12/30/caught-on-video-epxlosions-at-casselton-nd-train-derailment-evacuation-of-town-ordered/

This is why smart scanner buffs and smart fire buffs dont stand too
close to burning railroad cars

Is it a BLEVE? Looks like a BLEVE to me. Boiling Liquid Expanding
Vapor Explosion. You put some heat under a tank car full of petroleum
- let it cook for a while - then the metal fails - and - kabooomy.
Lots of energy in there - from both the petroleum and from the
exposure fire.

Why do we get a mushroom cloud? I dont know - ask a MIT professor. Or
look up 'mushroom cloud' at Wikipedia - the answer is probably there.
It has to do with vapors, heat transfer, laws of physics, etc.

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