I just read this:

"The main reason that some repair shops and other automotive professionals
choose to fill tires with nitrogen is to reduce a temperature swing’s
effect on tire pressure. “Nitrogen isn’t as susceptible to temperature
changes as oxygen,” says Karl Brauer, senior director of content for Kelley
Blue Book. “But our air has 78 percent nitrogen in it already, so you’re
not getting that much of a benefit from pure nitrogen versus regular air.”

Nitrogen does offer some advantages over regular compressed air when
filling tires. Since the molecules that comprise nitrogen’s chemical
structure are larger than oxygen’s molecules, nitrogen is less likely to
seep through rubber, the prime culprit for deflated tires. This keeps the
tire pressure more stable over the long term, especially during extreme
variations in temperature.

“Nitrogen-filled tires are less susceptible to temperature swings, so the
tires are more likely to maintain constant pressure under a wide variety of
temperatures and vehicle speeds,” says Ed Kim, vice president of industry
analysis at automotive research firm AutoPacific. “Part of this is due to
the intrinsic qualities of nitrogen over air, but part of this is also
because air has water vapor in it (humidity), and humid air is also more
susceptible to pressure changes as a result of temperature.”"

But I don't remember Boyles law being different for different gases. Are
the thermal expansion coefficients different for N and O?
-- 
OK Don

*“Travel is fatal to prejudice, bigotry and narrow-mindedness, and many of
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WILL ROGERS, *The Manly Wisdom of Will Rogers*
2013 F150, 18 mpg
2012 Passat TDI DSG, 44 mpg
1957 C182A, 12 mpg - but at 150 mph!
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