Printed Circuit Board Manufacturing Pollution Prevention Opportunities Checklist

Prepared by Alison Gemmell
CH2M Hill and
Philip Lo, CSDLA, 12/90.

Solid Waste Management
County Sanitation Districts Of Los Angeles County
1955 Workman Mill Road,
Whittier, CA 90603-4998

Mailing Address:

PO. Box 4998,
Whittier, CA 90607-4998

Charles W Carry
Chief Engineer and General Manager
Telephone (213) 699-7411, (213) 685-5217,
Fax: (213) 695-6139

The keys to pollution prevention in printed circuit board manufacturing are to minimize chemical dragout; minimize the amount of water used for ringing, and the recovery, reuse, and recycle of copper.

Y/N

Opportunities

Comments

 

I. Material Handling and Storage

 

Control inventory

Do not allow material to exceed shelf life.

 

Use materials on a first-in, first-out basis.

 
 

Buy appropriate amounts

Buy materials in small quantities if only small amounts are required.

 

Cover outdoor storage

Divert clean stormwater away from storage areas.

 

Install spill containment

Spills can be contained and managed. Reduces wastewater treatment upsets.

 

II. Dragout

 

Lengthen dragout time

Allows more chemical to drip back to process tank, so reduces the amount of chemical introduced in rinsewater.

 

Establish dragout timing

Post dragout times at tanks to remind employees.

 

Install drain boards

Boards and guards minimize spillage or drip guards between tanks and are sloped away from rinse tanks so dragout fluids drain back to plating tanks.

 

Install drip bare

Drip bars allow personnel to drain parts hands free without waiting, so personnel will not use too short a dragout time.

 

Mechanize dragout

Eliminates possibility of employee using too short a dragout time, maintains product QA/QC standards if timing is set properly.

 

Reduce pockets on parts

Place parts on dragout rack to minimize chances of chemical pooling In corners or in other packets.

 

III. Rinsing

 

Use static rinses

Static rinses usually follow the plating bath and capture the most concentrated dragout for returning to the plating bath or for metal recovery.

 

Use countercurrent rinses

These rinses dramatically reduce the amount of water required for rinsing and therefore reduce the amount of wastewater to be treated or sent for metal recovery.

 

Use conductivity sensor

This sensor gives an indication of the cleanliness of the rinsewater. Sensor can be designed to trigger clean rinsewater flow when the tank water gets too dirty.

 

Use spray or fog rinsing

Reduces rinsewater quantity required and can also be used over plating baths.

 

Use foot pump or photo

These items allow use of water only when sensor to activate rinse processing parts. A photosensor may be used on automatic plating lines.

 

Agitate rinse bath

Agitation promotes better rinsing. Agitate water or part.

 

Install flow restrictors

Restrictors automatically reduce the amount of rinsewater, so operators do not need to adjust inlet valves.

 

IV. Material Recycle, Reuse, and Recovery

 

Reuse deionized rinsewater

Depending on product, this rinsewater can be reused in a plating bath as evaporated water makeup.

 

Ion exchange on rinsewater

Ion exchange can be used to concentrate metals in rinsewaters and metal can be recovered from the ion exchange acid regenerant stream.

 

Reuse spent acid/alkaline

Spent acid can be used to neutralize an alkaline waste stream
Spent alkali can be used to neutralize an acid waste stream.

 

Reverse osmosis

Concentrate dragout for reuse in plating bath; the water stream can also be reused.

 

Evaporation

Concentrate dragout for reuse; the water condensate can also be reused.

 

Electrowinning

Recover metals from spent plating baths or ion exchange acid regenerant streams.

 

Reuse mild acid rinsewater

Use mild acid rinsewater as influent to rinse following alkaline cleaning bath. Improves efficiency of rinse, so less rinsewater is required.

 

Recover copper sulfate

On microetch line, recover copper sulfate crystals directly from etch tank and reuse crystals in copper electroplating baths.

 

Recover particulate copper

On debur operation, recover particulate copper using centrifuge or paper filter. Reuse water

 

Reclaim etchant

Send etchant to an off-site reclaimer instead of treating etchant in wastewater treatment system.

 

Reuse spent acids/alkalines

Use spent acids and alkaline solutions for neutralization reactions in wastewater treatment system.

 

Recycle photoresist stripper

Decant spent photoresist stripper from polymer residue and recycle stripper. Do not discharge spent stripper to wastewater treatment system.

 

V. Process Modification

 

Eliminate chelated baths

Change to a nonchelated plating bath to improve metal wastewater treatment. Chelated streams make it difficult to precipitate metal in wastewater treatment system.

 

Segregate waste streams

Increases recovery and treatment technology efficiencies. Acidic vs. alkaline. Concentrated metal (spent baths) vs. dilute metal (rinsewater streams). Chelated vs. nonchelated streams.

 

Convert to dry floor

Reduces chances of spills reaching floor drains or causing upset in wastewater pretreatment plant.

 

Buy efficient etch machine

An efficient etch machine results in less copper in rinsewater.

 

Increase bath temperature

Evaporates bath water so relatively clean waste rinsewater can be reused as bath makeup water
Reduces solution viscosity, so more chemical drains back to process tank during dragout.

 

VI. Process Operation and Maintenance

 

Use deionized (DI) water

Use DI water in plating baths, static rinses, and if practical in running rinses
DI water reduces impurities in the plating bath to extend its life and minimizes the precipitation of minerals in water as sludge.

 

Optimize bath concentrations

Only replace plating chemical when necessary.

 

Install bath filters

Lengthens bath life.

 

Replace chemicals on electroless copper baths

To extend bath life.

 

Automate chemical replacement through online analyzers and chemical flow meters.

 
 

Filters can remove particulates and trace contaminant organics in the process bath, lengthens bath life. Use filter that can be unrolled, cleaned and reused.

 
 

Raw material purity

Use high quality raw materials in bath so bath will not become contaminated as quickly.

 

Reduce bath dumps

Optimize bath operation so bath dumps are infrequent.

 

Spill cleanup procedures

Establish procedures for what to do with a Spill. Mitigates chance of spill being discharged to wastewater treatment plant.

 

Perform preventive maintenance

Routinely check for leaks in valves and fittings. Repair immediately.

 

Use continuous passivation on stainless steel components

In electroless plating tanks to prevent copper plate-out. Copper plate-out needs to be stripped with nitric acid. Reduces amount of spent nitric acid that needs to be treated

 

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