This fails now with a typed X::Syntax::Extension::TooComplex and a clear error message (see rakudo commit d0885e56e8):
$ perl6 -e 'sub infix:[/./] { say $^a, $^b }; 5@4' ===SORRY!=== Error while compiling -e Colon pair value '/./' too complex to use in name at -e:1 ------> sub infix:[/./]⏏ { say $^a, $^b }; 5@4 A test has been added to roast with commit 21a9ea0f2d I'm closing this ticket as 'resolved'.