Hi,

You could use PgMex (http://pgmex.alliedtesting.com/) - high-performance 
PostgreSQL client library for Matlab that enables a Matlab-based application to 
communicate with PostgreSQL database in the Matlab native way by passing data 
in a form of matrices, multi-dimensional arrays and structures. The library is 
written in pure C which gives a significant performance boost for both small 
and data-heavy database requests. Both Windows and Linux platforms are 
supported.

And PgMex does that much faster and for essentially greater volumes of data 
than Matlab Database Toolbox. For comparison of their performance see here: 
https://alliedtesting.github.io/pgmex-blog/2017/06/06/performance-comparison-of-postgresql-connectors-in-matlab-part-I/

Ilya

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