When you say that with a lot of concurrent access, queries get very slow, How 
many concurrent connections to your server have you had?
more that max_connections´value?
If you want to have many concurrent connections, you should have consider to 
use a pooling connection system like pgbouncer or pgpool.

Which are the values for:
- work_mem
- shared_buffers
- maintenance_work_mem
- effective_cache_size
- effective_io_concurrency
- server_version

Which are your platform?

Regards
--
Ing. Marcos Luís Ortíz Valmaseda
System Engineer -- Database Administrator

Centro de Tecnologías de Gestión de Datos (DATEC)
Universidad de las Ciencias Informáticas
http://postgresql.uci.cu


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