On Fri, 2022-07-15 at 18:07 -0700, Russell Senior wrote:
> On Fri, Jul 15, 2022 at 5:17 PM Tomas Kuchta
> <[email protected]> wrote:
> > 
> > On Fri, Jul 15, 2022, 17:04 Russell Senior <[email protected]>
> > wrote:
> > 
> > > I have used a bunch of these:
> > > 
> > >   https://www.amazon.com/gp/product/B00T0K8NXC/
> > > and
> > >   https://www.amazon.com/gp/product/B01G7BE9WK/
> > > 
> > > with https://github.com/merbanan/rtl_433 and an rtlsdr (like this:
> > > https://www.amazon.com/gp/product/B00VZ1AWQA/) to decode.
> > > 
> > > For improved accuracy, I calibrated the sensors in an icebath (in
> > > several layers of ziplock bags and desiccant) for 0 degrees offset.
> > > .
> > 
> > 
> > These are good sensors with great battery life. I also have ThermPro
> > sensors, they work, but the ones Russell lists are better, smaller and much
> > longer battery life.
> > 
> > I do not calibrate them. I care about being comfortable and saving power
> > rather than worry about whether the temperature reading is 0.2-0.3 degrees
> > different from absolutely correct value.
> 
> Fwiw, I didn't calibrate mine for a long time, but mine aren't so much
> for automated control, they were for understanding the temperature
> environments, and in particular differences and/or gradients in
> various microclimates. I noticed that a particular outside location
> seemed to get down to freezing before the other sensors. The
> significance of small temperature differences increases the closer you
> are to freezing, for example.  Eventually, I just wanted to understand
> whether the difference was due to the sensor or the microenvironment
> it happened to be in. Unless vigorously stirred, there can be
> significant temperature differences over very short distances, due to
> heat sources, stratification, illumination, etc.
> 
> I'd really like to have a lab grade temperature sensor, accurate to
> 0.01°C, to actually calibrate against. I encountered sensors when I
> worked in Oceanography with that kind of precision, but they were
> designed for water temperature and also were several thousand dollars.
> I wouldn't like to have one *that* much. Most consumer grade sensors
> only claim ±1°C.
> 

I was going to comment about - what atmospheric pressure did you calibrate your
sensors at - then I had second thought thinking about relatively high energy
needed/stored in H2O phase change which is connected to low dV (V-volume) on the
opposite sides of liquid/solid phase. H2O is very interesting substance indeed.

Anyway, I checked the theory, so I would not fool myself with the other smart
people here:

This is because of the Clausius-Clapeyron equation
dlogT / dlogP = (P dV) / L
where T is the temperature of the phase transition, dV is the change in volume,
and L is the latent heat. The water/gas transition has an enormous dV because
gas is much less dense than water, so dT/dP is large. The water/ice transition
has a dV about 10^-3, so dT/dP is small.

There is some 'cost' L to be paid doing the phase transition, most of it is paid
by thermal energy. If the volume changes during the transition, the P dV work
can help lowering the necessary temperature. So, it makes sense that dT/dP
depends on the ratio of these two contributions.

https://en.wikipedia.org/wiki/File:Phase_diagram_of_water.svg

So, as a consequence - water boils at low temperature on Mt. Everest or in
space, but ice cream is about as difficult to make at low/high pressures (unless
going above 1GPa+ (maybe there is a lot of ice(cream) in the middle of
sun/black-hole!)

Happy weekend, it should be ideal for temperature observations (with ice-cream)
-T

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