Thanks for sharing this Bruce!

On Mon, Jun 10, 2013 at 7:38 PM, Bruce Majors <[email protected]>wrote:

>
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> ---------
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> http://www.theatlanticcities.com/technology/2013/06/could-2000-year-old-recipe-cement-be-superior-our-own/5800/
> Could a 2,000-Year-Old Recipe for Cement Be Superior to Our Own?
>
>    - HENRY GRABAR <http://www.theatlanticcities.com/authors/henry-grabar/>
>    - JUN 07, 2013
>    - 7 
> COMMENTS<http://www.theatlanticcities.com/technology/2013/06/could-2000-year-old-recipe-cement-be-superior-our-own/5800/#disqus_thread>
>
> **[image: Could a 2,000-Year-Old Recipe for Cement Be Superior to Our
> Own?]**John Peter Oleson****
>
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> The Romans didn't invent concrete, but they did establish its versatility.
> The structural ingenuity of the Baths of Caracalla, the Pont du Gard and
> the Pantheon would not be surpassed for a thousand years.
>
> But if the dazzling concrete curves and cantilevers of modern architecture
> have matched the Romans' for style and structure, today's standard recipe,
> 2,000 years later, remains in some ways inferior.
>
> New 
> research<http://newscenter.lbl.gov/news-releases/2013/06/04/roman-concrete/> 
> into
> Pozzolanic cement, so named for the corner of the Bay of Naples where the
> ash of Mount Vesuvius facilitated its creation, shows the advantages of the
> Roman method. Their mixture for hydraulic concrete, a blend of volcanic ash
> and lime, has a tougher molecular structure than its modern equivalent.
> It's unusually resistant to fragmenting and nearly immune to the corrosion
> caused by salt water. That's why Roman jetties and port structures have
> weathered two salty millennia, while our maritime concrete creations
> degrade within a matter of decades.
>
> So why aren't we doing as the Romans did?
>
> For one thing, the methods largely vanished with the fall of Rome. "They
> really haven't been examined at a very fine scale until now," says Marie
> Jackson, one of the researchers who has been studying the molecular
> composition of Roman seawater concrete. "There's been a general lack of
> knowledge about what the Roman model could produce."
>
> One problem with ordinary Portland 
> cement<http://en.wikipedia.org/wiki/Portland_cement>,
> which is used, along with pebbles and sand, to make most of the modern
> world's concrete, is that it requires an enormous amount of energy. The
> lime and clay mixture must be heated at over 2,500 degrees Fahrenheit,
> making the manufacture of cement the third-largest 
> source<http://www.scientificamerican.com/article.cfm?id=cement-from-carbon-dioxide>
>  of
> greenhouse gas emissions in the U.S., and responsible for 5 to 10 
> percent<http://web.mit.edu/newsoffice/2007/concrete.html> of
> carbon dioxide production worldwide.
>
> In contrast the Roman method, recorded by Vitruvius, requires 10 percent
> less lime by weight and two-thirds the baking temperature, greatly reducing
> its environmental impact. It also has a molecular structure that insures
> strength and longevity, meaning that, like the piers of the great Roman
> harbors, it seldom requires replacement. Aluminum-rich ash, reacting with
> lime and seawater, forms a highly stable mineral called 
> tobormorite<http://en.wikipedia.org/wiki/Tobermorite>,
> which modern cement can only imitate.
>
> "What I'd like to see happen is that we learn to understand the fine-scale
> structure of this material, and begin at least experimental work to
> reproduce it so it can become a mainstream building material," Jackson says.
>
> *Top image: Soli-Pompeiopolis, with the concrete on the left. Courtesy of John
> Peter Oleson <http://web.uvic.ca/~jpoleson/>.*
>
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