Your alertmanager config is broken. "receivers" needs to be a list, as
does slack_configs, and the settings need to be indented. I doubt you're
even able to start alertmanager with that config.
You posted images rather than text, so I can't copy-paste your config to
fix it, but here's a different one showing the required formatting:
receivers:
- name: brian
email_configs:
- to: br...@example.com
send_resolved: true
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