I tried to open the file with Kate, trust me, it's an Excel file.
I'm using xlrd, it works beautifully (although come to think of it, I
haven't tried writing to an .xls file yet... hmmm)
> To clear up the doubts, I'd suggest that the OP do something like this
> at the Python interactive prompt:
>
> print repr(open('nasty_file.xls', 'rb').read(512))
>
> If that produces recognisable stuff, then it's a CSV file (or a tab
> separated file) masquerading as an XLS file.
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