I'll try .. lets see

 dput(dframe)
structure(list(PC1 = c(-112.131127281872, -116.596689350263, 
-128.974817313418, 1196.74257699487, 1216.80975908625, -162.017759589637, 
-85.3191578683763, -130.528496524968, -6.27985683466795, -110.832877061623, 
-127.466759201992, -106.169095838249, -135.615623230809, -140.740670692038, 
-163.111656805033), PC2 = c(-116.519244989851, 127.45362265627, 
-111.091607020859, -90.5227270764559, -123.103694889442, -92.620202365279, 
-31.3353634789021, -24.4646703348531, 627.701800243656, -5.87156108239855, 
-88.8993352468245, -106.166416491185, -95.3261810128253, -112.315850116593, 
-141.197051597155), PC3 = c(64.9404052536739, 259.296520455491, 
81.2617131909924, -40.2969961195199, -49.959279821408, 114.342573713326, 
-127.625681151677, 293.080433739631, -130.564246301803, 243.838480231849, 
-188.819145619591, -184.73732844957, 68.0106824426824, -202.00600443294, 
-3.31973728306762), PC4 = c(56.5233383519436, -188.28891646169, 
36.982033091297, 2.96535930848599, 38.9643424847775, 66.1927347587241, 
-70.2278717299823, 24.2000870994265, 85.41705362572, 81.3070906919206, 
-49.4076806523943, 44.4291395459566, 44.4189881931216, -47.787706169273, 
60.3084338394971), PC5 = c(-24.4330445432631, 119.03248964697, 
25.3182533898001, 2.22712423872515, 20.1564988015345, 8.58984063196041, 
-73.6618858270628, 154.531152822823, 80.0172481588946, -77.3997650093847, 
12.5317198856102, 16.7807094602606, 21.9728292529402, 18.0679363256966, 
14.8070821345172), PC6 = c(-3.51236160660659, 4.01466215993921, 
-14.0560600152898, 79.9790057450278, 63.8459665084246, 70.1505245709296, 
-9.72399636564978, -37.3441332401865, -20.0211154965333, 34.8148111484049, 
19.6697124222742, -12.5006014423202, -35.9412566332911, 43.8525592643803, 
49.0837309296695), PC7 = c(25.0416790893669, 29.2636829211613, 
58.5827246416567, 24.5865832216293, -3.79787182743163, 32.269692748727, 
9.13653843864113, 22.2828779024266, -1.74050522229119, -81.2339879700331, 
-8.39734635571791, 4.90076673663989, 26.3079758222854, -16.6096446464957, 
27.2347172477201), PC8 = c(-7.21492487063905, 41.4415040543379, 
-6.8561527559211, -9.6515803005436, 40.5578239936188, 35.6268320766844, 
4.33982606720149, -27.7334062748555, 1.58916911406888, 42.2854747927154, 
-19.0049848668069, 53.1381176037003, -43.7208819443017, -27.4638912504461, 
26.0693753249626), PC9 = c(5.07013225478207, 3.80978415808406, 
-12.9265139792091, 22.3706065788694, 43.9527567691036, 44.7661368799448, 
-25.6398826082422, 4.37103700086919, -9.0919050870289, 11.9520700564903, 
-23.250383344361, -30.3220249879799, -46.3887501545308, -14.0817576379036, 
16.168581787112), PC10 = c(-17.5630832749372, 52.568055046381, 
-9.07626573878839, -14.0951768936723, -5.23003343696749, 35.0154213026854, 
0.272344896140687, 13.3950601982445, -1.5533667315822, -40.8292771335063, 
-6.65959388343316, 5.06195872128945, -22.7857465669081, 6.62863071798569, 
18.3995069374505), PC11 = c(18.6010453343854, -28.4637751927999, 
1.71806569355502, 46.1205174166346, 9.53199967063977, 41.2972754904467, 
9.33464956019139, 23.3603727930995, 10.9744437554614, -0.126735591637572, 
21.8896623331257, -10.457965922839, -18.8322478793736, 27.7321423838636, 
28.4679654920173), PC12 = c(-2.22649901627144, 2.14317119837832, 
8.11993688993784, -1.02101828008616, -3.02022884335462, 3.99260060747241, 
-3.98208300398649, -8.73435109273014, -15.4116191493509, -21.9916390100063, 
-24.5400095100928, 11.7508407539612, -4.82585090072434, -21.4330004806799, 
4.07445502977139), PC13 = c(12.0478528474097, 19.1463355000476, 
-13.7614159178043, -2.45636501215998, 10.7570602509335, -27.124462677835, 
2.50581414841615, -1.43645727084062, -9.92501401886999, 14.541265924675, 
4.61925247518254, 31.9444025444124, 15.0123077631076, 1.73726777225125, 
-21.7438739224478), PC14 = c(-24.3652304503883, 21.1785358765272, 
0.221058054284211, -28.7788948242716, -0.840491052309543, 40.1941623968201, 
-17.1958234033114, 7.5770624168308, 7.45003285540585, 15.5283651855595, 
-8.65376069406027, 9.56538784228923, 4.23345479961019, -1.50016336971708, 
19.7559666669304), PC15 = c(9.92727520847547, -16.0078543011331, 
3.37100252722285, 26.8689400893287, 16.2203912046009, -6.07396584265131, 
-7.32119707525572, 0.194098009190007, -10.3216068605436, -23.0845947221256, 
0.696161095884098, -5.29057246485069, -1.79824229741562, -3.26507441975894, 
1.08088312906883), class = c(0, 1, 0, 1, 1, 0, 0, 1, 0, 0, 0, 
0, 0, 0, 0)), .Names = c("PC1", "PC2", "PC3", "PC4", "PC5", "PC6", 
"PC7", "PC8", "PC9", "PC10", "PC11", "PC12", "PC13", "PC14", 
"PC15", "class"), row.names = c("2396", "2754", "3645", "7122", 
"7106", "7172", "6761", "1599", "2107", "1865", "6795", "6913", 
"3329", "6836", "7229"), class = "data.frame")

These are 15 of my samples, and it seems to work with just that.

classifier<-ksvm(class~.,data=dframe,scaled=T,kernel="polydot",type="C-svc",
                        C=1,kpar=list(degree=5,scale=1,offset=0),prob.model=T)
pred.svm<-kernlab::predict(classifier,dframe[,1:15],type="probabilities");

cbind(pred.svm[,2],dframe$class)
            [,1] [,2]
 [1,] 0.29135615    0
 [2,] 0.03668269    1
 [3,] 0.29135845    0
 [4,] 0.03667823    1
 [5,] 0.03667505    1
 [6,] 0.35437992    0
 [7,] 0.29135892    0
 [8,] 0.03667943    1
 [9,] 0.29121498    0
[10,] 0.29121019    0
[11,] 0.29132637    0
[12,] 0.29135683    0
[13,] 0.29134198    0
[14,] 0.29132484    0
[15,] 0.29132652    0

Now that i managed to get me (and you) a closer look - seems like class labels 
switched maybe? pred.svm[,2] is named "1", but seems to have the probability to 
be class 0 in it.
This does not always occur however, you may have to run it a few times.

On 15.11.2012, at 16:47, Sarah Goslee wrote:

> Hi Jessica,
> 
> Talking may help you, but it's kind of a waste of time for the
> thousands of readers of R-help unless you provide a reproducible
> example and full context. We'd like to help, but can't without
> adequate information.
> 
> Sarah
> 
> On Thu, Nov 15, 2012 at 9:48 AM, Jessica Streicher
> <j.streic...@micromata.de> wrote:
>> Now i let it run for one specific set and got the same bad result, then i 
>> deactivated the probabilities and got a good result, then i activated the 
>> probabilities again and got a good result .. huh???
>> 
>> On 15.11.2012, at 15:32, Jessica Streicher wrote:
>> 
>>> Its not scaling.. so..
>>> 
>>> I guess i'll stay severely frustrated, and yes i know this is probably not 
>>> enough information for anyone to help.
>>> Still, talking helps ;)
>>> 
>>> On 15.11.2012, at 15:15, Jessica Streicher wrote:
>>> 
>>>> with
>>>> 
>>>> pred.pca<-predict(splits[[i]]$pca,trainingData@samples)[,1:nPCs]
>>>> dframe<-as.data.frame(cbind(pred.pca,class=isExplosive(trainingData,2)));
>>>> results[[i]]$classifier<-ksvm(class~.,data=dframe,scaled=T,kernel="polydot",type="C-svc",
>>>>             
>>>> C=C,kpar=list(degree=degree,scale=scale,offset=offset),prob.model=T)
>>>> 
>>>> and a degree of 5 i get an error of 0 reported by the ksvm object. But 
>>>> when doing
>>>> 
>>>> pred.pca<-predict(splits[[i]]$pca,trainingData@samples)[,1:nPCs]
>>>> pred.svm<-kernlab::predict(results[[i]]$classifier,pred.pca,type="probabilities");
>>>> results[[i]]$trainResults$predicted<-pred.svm[,2]
>>>> 
>>>> the results vary widely from the class vector. Nearly all predictions are 
>>>> somewhat around 0.29. Its just strange. And i have no idea where things go 
>>>> wrong. They're in the same loop with i, so its probably not an indexing 
>>>> issue.
>>>> 
>>>> Maybe kernlabs predict doesn't scale the data or something?
>>>> 
>>> 
> 
> 
> --
> Sarah Goslee
> http://www.functionaldiversity.org

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