I'll mail you some fine Si powder if you send me your address.

My best guess is that you have a relatively big lump of Si in your sample 
that happens to be lined up to make a bright spot from the bremstrahlung 
part of the spectrum.  It happens to meet some Si Bragg reflection 
condition for some wavelength in the brems. spectrum.

^~^~^~^~^~^~^~^~^~^~^~^~^~^~^~^~^~^~^~^~^~^~^~^~
Peter W. Stephens
Professor, Department of Physics and Astronomy
Stony Brook University
Stony Brook, NY 11794-3800
fax 631-632-8176

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