As others have pointed out outlook is purely a client connecting to, usually
exchange. For the purposes of firing off an email the only M$ option is an
exe called mapisend.exe which is a command line smtp mailer - it is part of
the back office resource kit. 

However that is charged for, personally I would use BLAT a decent, free
command line mailer and the following page is about how to use it with perl.

http://www.rrpro.com/support/webform_blat.asp
<http://www.rrpro.com/support/webform_blat.asp>  

Also whilst exchange can support LDAP, POP3, MIME etc. It will certainly
support SMTP, but one thing to watch out for is whether the server will
accept smtp connections from any IP address. Any security conscious mail
admin will lock down IP connection addresses (we do).

Hope this helps

Steve


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