Ok, my bad...

Missed the -crlf option because SMTP requires CRLF line endings.
STARTTLS works.

So actual conclusion: outlook.office365.com

SMTP: Plain SSL on Port 465 not accessible.
      STARTLS on 587 (and 25) works!
IMAP: STARTLS advertised but BROKEN on port 143 since 2 days.
      Plain SSL on Port 993 works!

Mit freundlichen Grüssen

-Benoît Panizzon-
-- 
I m p r o W a r e   A G    -    Leiter Commerce Kunden
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