Re: [meteorite-list] Etching Compounds

2004-09-13 Thread PeterUtas
Hey All,
You can also try going to your local hardware/pool supply store and pick up some pool-cleaning acid.  It's used to raise the ph of swimming pools.  It usually runs for under $10 a gallon.  I recently used some on a small nantan (bought for the experiment) and it ate all of the shale off in less than a day.  If you try this, make sure to put the acid in a well ventilated place, as it tends to make a strong sulfur-like smell as it works.  It should etch slices fairly well.  
Anyone else try this stuff?
Jason
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Re: [meteorite-list] Etching Compounds

2004-09-11 Thread David Freeman
Dear Stan;
My former experience isgo to the local water lab 
that samples wells/tests ground water. If you ask politely, one can get 
a 1/4 liter of Nitric if you tip the lowly lab tech with a specimen of 
meteorite and spend a few moments explaining what an interesting thing 
it is to be a meteorite collector...and an etching person! They get 
nitric many times in 5 gallon containers so a cup or so isn't a big thing.
Sometimes a 12 pack is the route to go but a REAL meteorite specimen 
will usually work.
Best,
Dave the acidman thread killer

stan . wrote:

Okay, now I know that I can't procure concentrated nitric acid 
without being employed by an institution of higher learning---unless 
I want to lie to the suppliers and tell them I'm a Professor of 
Inorganic Chemistry at Anthrax University or something. I'm no good 
at lying.

says who?
just open your phone book to chemical supliers and call one up - there 
are plenty of places that have retasil sales for lab chemcials - you 
might not find one locally if you are in the sticks, but it's far from 
difficult to get.

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Re: [meteorite-list] Etching Compounds

2004-09-11 Thread stan .

Okay, now I know that I can't procure concentrated nitric acid without 
being employed by an institution of higher learning---unless I want to lie 
to the suppliers and tell them I'm a Professor of Inorganic Chemistry at 
Anthrax University or something.  I'm no good at lying.

says who?
just open your phone book to chemical supliers and call one up - there are 
plenty of places that have retasil sales for lab chemcials - you might not 
find one locally if you are in the sticks, but it's far from difficult to 
get.

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Re: [meteorite-list] Etching Compounds

2004-09-11 Thread VeIocity
Okay, now I know that I can't procure concentrated nitric acid without being employed 
by an institution of higher learning---unless I want to lie to the suppliers and tell 
them I'm a Professor of Inorganic Chemistry at Anthrax University or something.  I'm 
no good at lying.

So, following somebody's sage advice, I just bopped down to Radio Shack and picked up 
a pint of etching solution for about five bucks.  Ferric Chloride, but I'm not sure 
what concentration.  I assume that, even at full strength, FeCl3 requires more 
reaction time than does Nitrol.  Anybody have experience with FeCl3, or give me an 
idea of how long I should allow it to react?  BTW, I'm plan to use it on Campo and 
Canyon Diablo.

VeIocity
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Re: [meteorite-list] Etching Compounds

2004-09-11 Thread stan .

Of course, the down side of using fluoridated compounds is that they can
MAKE YOU DIE!  ...or just get burned very badly and end up in the
hospital.

not to belittle the hazards of flourine, but let's keep things in 
perspective - just because something can kill you doesnt mean it cant be 
used when handled with due caution - after all drinking too much water can 
kill you, yet there is no reason to fear water.

I'd say it's a pretty safe bet that the acid solution Adam talked about 
contained nitric acid. IF thats the case then the brownish gas that was 
evolved was nitrogen dioxide - a VERY toxic gas with a lethal concentration 
ten times LOWER than that of hydrogen cyanide - the stuff that was used in 
gas chambers to execute condemned prisoner. (LC50 of 200 ppm for 1 minute vs 
2000 ppm for 1 minute for HCN). When viewed in that perspective a little bit 
of flourine here and there doesnt seem so bad.

in short - so long as you take proper safety precuations when using such 
materials you can use the stuff without worry - but sloppy chemical hygene 
can cause serious injury or, aqs you pointed out - death.

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Re: [meteorite-list] Etching Compounds

2004-09-11 Thread Marc D. Fries
Of course, the down side of using fluoridated compounds is that they can
MAKE YOU DIE!  ...or just get burned very badly and end up in the
hospital.

For those of y'all who subscribe to Discover magazine, they had one of
their "Vital Signs" articles about a hydrofluoric acid burn a few years
ago.  It's enough to turn you away from using fluorinated compounds ever
again:

http://www.discover.com/issues/apr-96/departments/aninvisiblefire739/

Be careful with that stuff - fluorine is a small enough atom that it soaks
right through your skin and attacks your arteries and heart instead of
"just" burning your skin.

Cheers,
MDF

> in my very Very VERY limited experience a solution of ammonium biflouride
> in
> phosphoric acid makes an excellet 'cleaning potion' for iron meteroties. I
> was quite skeptical of it's usefullness due to the flourine content, but
> the
> small sikhote i cleaned over a year ago is in perfect shape today - and
> it's
> a 'shower' - gets passed around to friends and sits around unprotected in
> the wet florida weather. a nice added bonus is that if left on a metal to
> be
> cleaned it leaves a layer of black iron oxide, somewhat hiding the cleaned
> areas in fusion crusted irons.
>
>
>

---
Marc D. Fries, Ph.D.
Postdoctoral Research Associate
Carnegie Institution of Washington
Geophysical Laboratory
5251 Broad Branch Rd. NW
Washington, DC 20015
PH:  202 478 7970
FAX: 202 478 8901
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Re: [meteorite-list] Etching Compounds

2004-09-10 Thread stan .
in my very Very VERY limited experience a solution of ammonium biflouride in 
phosphoric acid makes an excellet 'cleaning potion' for iron meteroties. I 
was quite skeptical of it's usefullness due to the flourine content, but the 
small sikhote i cleaned over a year ago is in perfect shape today - and it's 
a 'shower' - gets passed around to friends and sits around unprotected in 
the wet florida weather. a nice added bonus is that if left on a metal to be 
cleaned it leaves a layer of black iron oxide, somewhat hiding the cleaned 
areas in fusion crusted irons.


From: "Adam Hupe" <[EMAIL PROTECTED]>
To: <[EMAIL PROTECTED]>
Subject: Re: [meteorite-list] Etching Compounds
Date: Fri, 10 Sep 2004 12:45:53 -0700
Hello List,
This topic reminds me of the "Magic Cleaning Potion" we purchased from a
hippie at the Denver show last year.  We figured it was a combination of
acids after accidentally reverse etching some Tazas with it.  He was right
this potion was capable of cleaning things. Not only did it etch our Tazas
from the outside-in giving them a 3D appearance, it disintegrated a 2'
square hole in our driveway after eating through a seam in a tin bucket. We
can hardly wait to give this dude a piece of our mind this year as this
potion gassed us out of our shop with a noxious brown cloud and damaged a
bucket, ~ 400 grams of Tazas and our driveway.  Be careful when using any
type of acids to etch or clean with.
All the best,

Adam Hupe
The Hupe Collection
Team LunarRock
IMCA 2185
[EMAIL PROTECTED]
- Original Message -
From: <[EMAIL PROTECTED]>
To: <[EMAIL PROTECTED]>; <[EMAIL PROTECTED]>
Sent: Friday, September 10, 2004 11:49 AM
Subject: Re: [meteorite-list] Etching Compounds
> Hola,
> Concentrated nitric acid is about 16 molar (70%).
>
> You don't want any water you can avoid.  It is then diluted (by pouring
acid into alcohol) down to "1 molar" (16:1 vol/vol), but in quotes because
that should be with anhydrous, or 95% minimum ethyl alcoholI usually
consider "molar" as in water, hence the important clarification.
> Doug
>
> careful and have fun drawing figures:)
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Re: [meteorite-list] Etching Compounds

2004-09-10 Thread Adam Hupe
Hello List,

This topic reminds me of the "Magic Cleaning Potion" we purchased from a
hippie at the Denver show last year.  We figured it was a combination of
acids after accidentally reverse etching some Tazas with it.  He was right
this potion was capable of cleaning things. Not only did it etch our Tazas
from the outside-in giving them a 3D appearance, it disintegrated a 2'
square hole in our driveway after eating through a seam in a tin bucket. We
can hardly wait to give this dude a piece of our mind this year as this
potion gassed us out of our shop with a noxious brown cloud and damaged a
bucket, ~ 400 grams of Tazas and our driveway.  Be careful when using any
type of acids to etch or clean with.

All the best,



Adam Hupe
The Hupe Collection
Team LunarRock
IMCA 2185
[EMAIL PROTECTED]


- Original Message - 
From: <[EMAIL PROTECTED]>
To: <[EMAIL PROTECTED]>; <[EMAIL PROTECTED]>
Sent: Friday, September 10, 2004 11:49 AM
Subject: Re: [meteorite-list] Etching Compounds


> Hola,
> Concentrated nitric acid is about 16 molar (70%).
>
> You don't want any water you can avoid.  It is then diluted (by pouring
acid into alcohol) down to "1 molar" (16:1 vol/vol), but in quotes because
that should be with anhydrous, or 95% minimum ethyl alcoholI usually
consider "molar" as in water, hence the important clarification.
> Doug
>
> careful and have fun drawing figures:)
> __
> Meteorite-list mailing list
> [EMAIL PROTECTED]
> http://six.pairlist.net/mailman/listinfo/meteorite-list


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Re: [meteorite-list] Etching Compounds

2004-09-10 Thread MexicoDoug
Hola,
Concentrated nitric acid is about 16 molar (70%).

You don't want any water you can avoid.  It is then diluted (by pouring acid into 
alcohol) down to "1 molar" (16:1 vol/vol), but in quotes because that should be with 
anhydrous, or 95% minimum ethyl alcoholI usually consider "molar" as in water, 
hence the important clarification.
Doug

careful and have fun drawing figures:)
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[meteorite-list] Etching Compounds

2004-09-10 Thread VeIocity
What's a good source for etching compounds, such as concentrated nitric acid?  Is a 6m 
nitric too heavy for etching?  Something lighter, maybe 1m nitric?  Thanks for your 
replies and suggestions!

VeIocity
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