http://news.wustl.edu/news/Pages/23097.aspx

http://news.wustl.edu/news/Pages/23097.aspx

 

$1.38 million to pick 'large' pieces of supernova grit out of meteorite

 
Tour de force experiment to reveal how elements that make up our bodies and our 
planet were forged 
December 12, 2011 
By Diana Lutz 
 
Joe Angeles/WUSTL

Ernst Zinner, and Ann Nguyen, then a doctoral student in earth and planetary 
sciences, study a grain of stardust in the NanoSIMS (Secondary Ion Mass 
Spectrometer) lab at Washington University in St. Louis.
Ernst K. Zinner, PhD, research professor of physics and earth and planetary 
sciences in Arts & Sciences has received a three-year, $1,380,000 grant from 
the National Aeronautics and Space Administration (NASA) to study presolar 
grains in a sample of the Murchison meteorite, a primitive meteorite that fell 
to Earth near the town of Murchison, Australia, in 1969.

Presolar grains are literally tiny bits of stars — stardust — that were born 
and died billions of years ago, before the formation of the solar system.

>From a generous chunk of the meteorite, Zinner hopes to extract exceptionally 
>large grains that came from supernovae, giant stars that exploded at the ends 
>of their lives. The larger grains will allow him to make more comprehensive 
>measurements and, in turn, achieve a clearer understanding of what happened in 
>these long-extinct stars -- where most of the elements that make up our bodies 
>and our Earth were forged.

Until the 1960s, most scientists believed that the early solar system got so 
hot that presolar material could not have survived intact. However, in the 
mid-1960s, researchers started finding unusual isotopic ratios of the noble 
gases neon and xenon in certain types of meteorites. The fact that these 
volatile gases were still there suggested that they were trapped in very 
refractory (heat-resistant) mineral grains.

In 1987, Ed Anders and his co-workers at the University of Chicago and Zinner 
and his colleagues at WUSTL succeeded in identifying diamond and silicon 
carbide as the noble gas carriers. This was achieved by dissolving meteorites 
in acid, a method described by Anders as "burning down the haystack to find the 
needle.”

 
Wikimedia Commons

A piece of the Murchison meteorite on display at the National Museum of Natural 
History in Washington, D.C. Ernst Zinner will be studying roughly 100 grains of 
supernova dust he will extract from half a kilogram of the meteorite by 
dissolving the rest in acids.
Presolar grains are very small, typically only a few millionths of a meter 
across, so sophisticated instruments are needed to study them. Zinner will be 
using an ion microprobe, a type of Secondary Ion Mass Spectrometer, or SIMS, 
instrument that achieves high spatial resolution by using a finely focused ion 
beam. Zinner himself developed many of the techniques that allow the microprobe 
to perform such precise analytical work.

SIMS works by sandblasting a sample and passing the electrically charged debris 
that comes flying off through electric and magnetic fields that sort it by 
mass. The masses, in turn, identify individual elements and their isotopes.

The isotopic compositions of the grains allow the scientists to understand the 
evolution of the stars from which the grains originated, especially the nuclear 
processes that created the elements of which the grains consist.

“What I want to do in this project,” Zinner says, “is to locate as many 
supernova grains as possible that are large enough that we can do measurements 
of many different elements.

“Presolar grains have survived in the Murchison meteorite,” Zinner says, 
“because it is primitive, or unprocessed. It is a piece of an asteroid that was 
small enough that the rock never melted or separated according to density.

“We’ll extract the silicon carbide grains by using a series of acids to 
dissolve away the rest of the meteorite. It’s a simple process,” he says, “but 
it took 20 years to figure out it was possible.

“We’ll start with half a kilogram of Murchison, which is a lot,” he says. 
“Usually people don’t want to give you more than a few grams of a meteorite. 
But fortunately quite a lot of material fell at Murchison, about 200 kilograms, 
so we could obtain a large amount of it.”

 
Scott Messenger

A silicon carbide grain is only a few microns across, smaller than a yeast cell 
or red blood cell, but it has traveled across space and time bearing the 
secrets of its parent star within it.
The silicon carbide grains are only a small fraction of the meteorite, and 
Zinner wants to select only the biggest of them, those that are five microns in 
diameter or bigger. Once he has his big grains, he’ll separate those 
originating from supernova from those originating in red giants.

This will be done by isotopic analysis, he explains. One of the silicon 
isotopes is mostly made in supernovae, he says, and by looking at the silicon 
isotopic composition, the ion probe can sort the grains automatically.

“In short,” he says, “the process will be to dissolve the meteorite, then 
collect the silicon carbide grains, then separate the silicon carbide grains 
according to size, and finally analyze the isotopic composition of the big 
grains to find the supernova grains.”

“We hope to end up with roughly 10,000 five-micron grains and of those perhaps 
100 will be supernova grains,” Zinner says.

Only then will the real work begin. Because supernova grains are rare and most 
are very small, studies of supernovae grains have so-far yielded only patchy 
information. By working with large grains Zinner hopes to be able to make much 
more comprehensive measurements.

If he’s lucky, he says, his findings will narrow the constraints on theoretical 
models of supernovae and the production of elements within them. The Big Bang 
created only the lightest elements, hydrogen and helium, he says. Red giants 
make the elements up through oxygen, but  the oxygen remains in the star when 
it ejects its outer layers and becomes a white dwarf. Most of the oxygen in the 
solar system and all of the elements heavier than oxygen were created in the 
bellies of supernovae, some in the death throes of these stars by a process 
called explosive nucleosynthesis.

It is hard to imagine science with more profound implications; if the elements 
made in the nuclear furnaces of supernovae did not exist, we would not exist. 
We are all, as has been famously said, made of stardust. 
 
                                          
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