[biofuel] Re: Help with Making Biodiesel from WVO

2001-10-03 Thread Aleksander <kac

Ian,
> 2Material fully reacts but no glycerol separates - I have tried 
adding water after 24 hours but there seems to be a very high water 
tolerance leading to a very inefficient split of ester to 
glycerol/water.
Material doesn't react. The only sign of a transesterification 
reaction is separation. get rid of the water in your oil/alcohol.

> I have read most of the material found easily on the web and tried 
direct esterification with sulfuric acid or phosphoric acid as a 
starting point but without consistent success.
Phosphoric acid doesn't catalize. Acid catalized 
esterification/transesterification requires anhidrous conditions, 
works with H2SO4 95% or more, reflux of dehidrated alcohol would be 
suitable. Reactiond should be done at 45 deg C or higher. Alcohol 
should be introduced at min 5 mol per mol of oil to a max of 6 mol 
per mol of oil. Acid catalized reactions can't be done to perform a 
100% conversion.
Aleks



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Re: [biofuel] Help with Making Biodiesel from WVO

2001-10-03 Thread Ken Provost

Ian writes:


>2Material fully reacts but no glycerol separates - I have tried 
>adding water after 24 hours but there seems to be a very high water 
>tolerance leading to a very inefficient split of ester to 
>glycerol/water.


With particularly high-FFA WVO (which yours must be to give such 
gelling problems),
I've found straight ethanol, even totally anhydrous, will fail to 
give separation.
The only fix I've found is to include some methanol (say 15% of your 
total alcohols)
in the mix. If your alcohol is already denatured with some methanol, you won't
need to add as much, of course.

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[biofuel] Help with Making Biodiesel from WVO

2001-10-03 Thread [EMAIL PROTECTED]

Hello All,
I'm fairly new to this group and have been lurking in the wings for a while now.
I must admit there is certainly a lot of traffic (no pun intended)
Anyway, down to business

I have been experimenting with Rapeseed oil to make a form of biodiesel using 
ethanol as the alcohol fraction to make ethyl esters.
When I try making a similar product using waste frying oil I find the following 
problems:
1Material gels with sodium hydroxide catalyst - largely overcome by adding 
a little extra ethanol at the start or using potassium hydroxide (Filtration of 
a WVO/ethanol mix through lime helps remove excess interfering free fatty 
acids.)
2Material fully reacts but no glycerol separates - I have tried adding 
water after 24 hours but there seems to be a very high water tolerance leading 
to a very inefficient split of ester to glycerol/water.
3Distilling excess alcohol from the mix once the reaction has completed 
does not seem to help clean WVO ester but does improve fresh veg oil esters.
4Varying the catalyst level does not seem to help. A minimum critical 
quantity is needed excess just gets in the way. (I don't normally titrate but 
make a series of mini batches to get the best reaction)

I have read most of the material found easily on the web and tried direct 
esterification with sulfuric acid or phosphoric acid as a starting point but 
without consistent success.
Can anyone shed any light on these matters?
Many thanks,

Ian






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[biofuel] EFI & Gasifiers

2001-10-03 Thread Harmon Seaver

 Has anyone every tried running an engine with EFI on a gasifier (or
even on propane)? Obviously the woodgas isn't going to be running thru
the injection system itself, per se, but if it was piped into the air
intake somewhere -- not sure if you'd want it upsteam or downstream of
the airflow meter, since that changes mixture according to air temp as
well as flow.
 Probably would be okay to let it use *some* gasoline, you'd get
better power, but I'd think it would only use minimal amounts.

--
Harmon Seaver, MLIS
CyberShamanix
Work 920-203-9633
Home 920-233-5820
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Re: [biofuel] 'Old smokey was More Ballard (fuel cell)

2001-10-03 Thread Edward Beggs

Did they sell early Hyundai's where you live?

;-)


- Original Message -
From: "MH" <[EMAIL PROTECTED]>
To: 
Sent: Wednesday, October 03, 2001 1:22 PM
Subject: Re: [biofuel] 'Old smokey was More Ballard (fuel cell)


> I seen one this year. Its been a few years since I've seenum out in force.
> In fact blacksmokebelchingsemis are a rare occurrence for me. Must be
working.
>
> > ...And while we're at it, let's work harder to haul those
super-emitters
> > (bluesmokewornguidesandringspetrolcars) off the road. They're worse to
> > follow than an old diesel. It's ridiculous to spend one dime on
programs,
> > research, and new technology when we still let those run around - might
as
> > well just give those of limited means some money to get those things
tuned
> > up and fixed, we'd be further ahead.
>
> Biofuel at Journey to Forever:
> http://journeytoforever.org/biofuel.html
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>
>


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Re: [biofuel] 'Old smokey was More Ballard (fuel cell)

2001-10-03 Thread MH

I seen one this year. Its been a few years since I've seenum out in force. 
In fact blacksmokebelchingsemis are a rare occurrence for me. Must be working. 

> ...And while we're at it, let's work harder to haul those  super-emitters
> (bluesmokewornguidesandringspetrolcars) off the road. They're worse to
> follow than an old diesel. It's ridiculous to spend one dime on programs,
> research, and new technology when we still let those run around - might as
> well just give those of limited means some money to get those things  tuned
> up and fixed, we'd be further ahead.

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[biofuel] 'Old smokey was More Ballard (fuel cell)

2001-10-03 Thread Edward Beggs

Nice, for the RV crowd, but silent power for RV's is already available in
the form of PV panels, so is this application going to go anywhere if it
costs more than those? Anyway, outfitting an RV with a fuel cell will
accomplish nothing in terms of air quality, which is why we're all supposed
to be  all excited about fuel cells.

Meanwhile,

There are about 200 million diesels in the world, and 20 million more built
every year, and demand is growing. These will be in service for decades. It
will be a while before fuel cells take over the market. Meanwhile there is
about a 50 year need for biodiesel and ethanol as at least a portion of the
fuel used.

 Urban air would be a lot more pleasant if all diesels were running ULSD and
B20. With the health effects that have now been attributed to petroleum
diesel exhaust, there is no excuse not to bring those emissions down today.
Biofuels are the cheapest, easiest way to do that.

Tell the politicians and regulators the diesel is ok for now, but the fuel
must be improved dramatically - and tell them how it can be cleaned up
considerably. We don't have to be able to drink the exhaust - just to be
able to breath in the same vicinity as a transit bus or dump truck would be
nice.

...And while we're at it, let's work harder to haul those  super-emitters
(bluesmokewornguidesandringspetrolcars) off the road. They're worse to
follow than an old diesel. It's ridiculous to spend one dime on programs,
research, and new technology when we still let those run around - might as
well just give those of limited means some money to get those things  tuned
up and fixed, we'd be further ahead.

Ed B.
www.biofuels.ca










- Original Message -
From: "Dana Linscott" <[EMAIL PROTECTED]>
To: 
Sent: Wednesday, October 03, 2001 10:28 AM
Subject: Re: [biofuel] More Ballard (fuel cell)


>
> --- Dana Linscott <[EMAIL PROTECTED]> wrote:
>
> According to this WSJ article Ballard released its'
> "first commercial product, a fuel-cell module for
> stationary or portable uses" last week.
>
> http://public.wsj.com/sn/y/SB1002049259455819160.html
>
> I wonder if this isn't the Coleman/Pwermate product?
>
>
> Theres more!
>
> "On the road, fuel cells are likely to begin powering
> small numbers of vehicles within the next two to three
> years. But several manufacturers, including Ford,
> DaimlerChrysler and GM, have said it will be the end
> of the decade before they might start selling large
> numbers of fuel-cell-powered cars and trucks."
>
> Dana
>
>
>
>

/
>
>


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Re: [biofuel] More Ballard (fuel cell)

2001-10-03 Thread Dana Linscott


--- Dana Linscott <[EMAIL PROTECTED]> wrote:

According to this WSJ article Ballard released its'
"first commercial product, a fuel-cell module for
stationary or portable uses" last week.

http://public.wsj.com/sn/y/SB1002049259455819160.html

I wonder if this isn't the Coleman/Pwermate product?


Theres more!

"On the road, fuel cells are likely to begin powering
small numbers of vehicles within the next two to three
years. But several manufacturers, including Ford,
DaimlerChrysler and GM, have said it will be the end
of the decade before they might start selling large
numbers of fuel-cell-powered cars and trucks."

Dana




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Re: [biofuels-biz] small production plant

2001-10-03 Thread Mauro Knudsen


 Hello John Cromarty and all, if you want to build yourself the biodiesel 
reactor for waste vegetable oil, look this web:
http://journeytoforever.org/biodiesel_simon.html
and
http://www.veggiepower.org.uk/
The last one is from UK like you.
Best regards,
 Mauro Ariel Knudsen.
 



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[biofuels-biz] Cetane Number

2001-10-03 Thread Mauro Knudsen


Hello all, some days ago I readed a discution about Cetane Number from diferent 
fuels (Diesel 1 and 2, and Biodiesel), if anyone wants to know, how many cetane 
number had the diferent biodiesels (depending on raw material used and alcohol 
used) you can see all this information in:

http://journeytoforever.org/biodiesel_yield.html

 Best regards,

   Mauro Ariel knudsen.

 



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Re: [biofuel] Disney land in December?

2001-10-03 Thread Fischmann

Disney land is in California. Disney World is in Florida. 


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Re: [biofuel] More Ballard (fuel cell)

2001-10-03 Thread Dana Linscott

Hi Robert,

It is my understanding that Ballard has sold quite a
few fuel cells though of course it would be difficult
to walk in and purchase one at the moment. I suppose
these could be considered "working prototypes" as they
are the first production from their manufacturing
facilities and as I understand it mostly consisted of
stationary powerplants constructed of huge banks of
their currently produced proprietary fuel cell. Word
was that these units were as much to get hours on the
cells in an extended test as to generate profit
(mostly from the news of the fuel cell sales) so the
term working prototype might  be appropriate. If I
recall correctly most of these were sold to customers
in Japan and were to be run on natural gas as a fuel
source.

Coleman (Powermate) recently announced that it expects
to have Ballard fuel cell RV generators for sale
within the next year as well. Logical use as folks
that are willing to pay the big bucks for a RV won't
mind the initial cost and won't have to turn off their
generators to allow their neighbors to sleep as they
do now in most RV parks.

 Also didn't an American automaker just put in a 20
million dollar order for the first production units
designed for cars less than a month ago? It seems to
me that some of the recent mergers may be designed to
allow a quick ramp up in production to beat out their
competition in the near future. Of course it could all
be clever corporate manipulation of their stock
values. Lord knows that is not uncommon.

I agree that even given their reputed efficiency their
initial cost will have to drastically decline before
they approach the economic efficiency of diesels. I am
nearly certain that the first million fuel cell
powered vehicles will be grossly overpriced and
probably less reliable that conventional powerplants.
Still I see the heavy investment in Ballard and other
fuel cell research companies by large corporations who
want some control of their product as a positive sign.


And of course fuel cells are not pollution free...just
less polluting than our current powerplants.
Except of course WVO/SVO/and BD fueled vehicles.

Dana
>snip<

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[biofuel] Disney land in December?

2001-10-03 Thread k5farms

WOBURN, Mass.--(BUSINESS WIRE)--Oct. 3, 2001--The Center for Business 
Intelligence is proud to announce it's 4th Business Case for Fuel 
Cells conference, to be held December 3-4, 2001 at The Omni Colonnade 
in Miami, FL. 

Hear the latest technologies, applications, markets and investments 
opportunities for Fuel Cells at CBI's 4th Business Case for Fuel 
Cells conference. The program addresses what private equity companies 
look for when identifying new technology investment opportunities. 
Attend this conference and examine, learn and understand issues such 
as: 

The operating cost differential between fuel cells and traditional 
generation for industrial customers
How using fuel cells during times of peak demand can minimize risks 
and costs- Compare to other temporary power alternatives
Siting fuel cells systems- Determine where they will have the biggest 
impact on reliability to end users 
Special Highlighted Presentation: 

Achieve Market Penetration for Solid Oxide Fuel Cells, Led by: Dr. 
Subhash Singhal, Pacific Northwest National Laboratory
A Case Study on the Texas Fuel Cell Partnership- Using Fuel Cells to 
Power Emissions Monitoring Equipment 
Plus! Choose from 2 Pre-Conference Workshops on Monday, December 3, 
2001: 

Workshop A- A Primer- Fuel Cell Technology and Commercialization 
Update 

Workshop B- Developing Automotive and Transportation Applications for 
Fuel Cells 

CBI's 4th Business Case for Fuel Cells conference is a great way to 
network with colleagues and clients! We look forward to seeing you on 
December 3, 2001 in Miami, Fl. 

To Register, or for more information, contact Glen Manseau, PH: 781-
939-2513 or e-mail [EMAIL PROTECTED] Please mention your priority 
code, PB173PR 



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[biofuel] Now they might be showing up in your local junk yard!!

2001-10-03 Thread k5farms

Accidents happen every day and then they end up in scrap yards, talk 
to your insurance agent and ask them!

EL SEGUNDO, Calif.--(BUSINESS WIRE)--Oct. 3, 2001--AURA SYSTEMS, INC. 
(OTC BB: AURA - news) announced today that the Ford Motor Co. will 
feature the AuraGen/ICS (inverter charger system) on two F-Series 
trucks. The trucks will be part of the Ford exhibit at the 
International Truck and Bus Meeting and Exhibition (ITB) to be held 
at the Navy Pier in Chicago on November 12-14. ITB is sponsored by 
the Society of Automotive Engineers (SAE). 

The AuraGen ICS option turns the AuraGen into a complete power 
management system. The system provides AC power to the truck user 
either with the truck engine operating or with the engine off. The 
transitions between the engine on and off modes are totally 
transparent to the user both operationally and in power quality, 
without any spikes or interruptions. The ICS requires an auxiliary 
battery pack, which is used to provide the power, while the engine is 
off. When the battery charge is low the user is alerted by the system 
to turn the engine on. As soon as the engine is turned on the system 
switches the power generation to the AuraGen and simultaneously 
charges the battery pack. Secondarily, the AuraGen/ICS system is used 
during driving to draw energy for power spikes from the battery 
complement without affecting the engine idling speed or operation in 
any way. The system also provides DC power for 12 or 24-Volt systems 
and will be available for 42-Volt systems where required. 

Aura designed the new AuraGen ICS system to answer needs in a variety 
of industries. Some of the industries include Emergency/Rescue 
vehicles including police, medical and fire; Recreational vehicles; 
mobile food catering; telecommunications; municipal services; and 
long distance hauling. 

For more information about the AuraGen, see the company's website, 
http://www.aurasystems.com/. Aura Systems, Inc., a leader in 
electromagnetic systems, is located in El Segundo, CA. 



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[biofuels-biz] info for Steve Spencer

2001-10-03 Thread Jan Sur—wka

Hi Steve,

With regard to the Polish plant - I think they just do not have it in their 
offer.

jan
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Re: [biofuel] More Ballard (fuel cell)

2001-10-03 Thread steve spence

efficiency. it requires energy to get the hydrogen out of the hydride. heat
from an ICE could be used for this purpose.

Steve Spence
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- Original Message -
From: "kirk" <[EMAIL PROTECTED]>
To: 
Sent: Wednesday, October 03, 2001 2:50 AM
Subject: RE: [biofuel] More Ballard (fuel cell)


> How about hydride storage and for purity an aluminum molecular seive?
>
> -Original Message-
> From: robert luis rabello [mailto:[EMAIL PROTECTED]
> Sent: Tuesday, October 02, 2001 11:01 PM
> To: biofuel@yahoogroups.com
> Subject: Re: [biofuel] More Ballard (fuel cell)
>
>
>
>
> Dana Linscott wrote:
>
> > Here is some more recent info on what I consider the
> > leader in fuel cell technology. These folks are
> > actually selling fuel cells right now. Major
> > investments have been made in Ballard by big
> > automakers in the past few years. Too much money to be
> > a "red herring".
> >
> > http://biz.yahoo.com/mf/011002/plate_011002.html
> >
> > Dana
>
> Hello Dana!
>
> Ballard hasn't sold a single fuel cell it its history.  What they have
> done is develop working prototypes, and they're selling manufacturing
> licenses to interested companies.  You cannot go to Ballard and buy a fuel
> cell.  (In fact, you'll have a VERY hard time getting past the reception
> area!)
>
> Yes, the auto makers are setting up license agreements, and yes, money
> is
> changing hands, but the money is buying control, not product.  If you read
> the article you've linked to, you will learn that nobody has actually paid
a
> penny for a fuel cell.  Here's a quip:
>
> "Ballard will also get a significant cash infusion from Daimler and Ford.
> Combined, the automakers will invest
> an additional $69 million in Ballard, which will only add to Ballard's
> impressive war chest.
>
> The automakers have extended not only their investment in Ballard, but
also
> their operational dependency. The
> new 20-year alliance between Ballard and both Daimler and Ford will be
much
> simpler -- and cheaper -- than
> the old alliance, and seemingly assures Ballard of customers when its
> automotive fuel cells are ready for the
> market, hopefully sometime in the next two to four years."
>
> Note the word "hopefully".  Note the "two to four year" time frame.
> I've
> been hearing this kind of thing for a long time, and I have become quite
> skeptical!
>
> Personally, I hope Ballard can make its fuel cell technology work.  I
> hope they can make a killing selling fuel cell licenses to the automobile
> industry.  (Ballard is a local company up here.)  I would LOVE to see a
> "hydrogen economy" come to fruition, but I've been waiting for over thirty
> years for this to happen, and vexing problems remain.  The biggest one
stems
> from the fact that nobody has figured out the storage problem, and the PEM
> fuel cells Ballard has developed require hydrogen of exceptional purity.
>
> Steve Spence posted a link to a company a couple of days ago.  If
you're
> interested in hydrogen, this should intrigue you:
>
>
http://www.millenniumcell.com/solutions/white_hydrogen.html
>
> Even with fuel cells driving electric motors, a good diesel engine is
> still very hard to beat, and the technology to produce them, as well as
the
> infrastructure to fuel them, is already well developed.  Perhaps we should
> be
> exploring supplemental H2 injection in diesel engines as a way to reduce
> emissions and remove the only REAL drawback to modern diesels.  Why waste
> your time with fuel cells when a small diesel, driving a gen set, will
power
> a hybrid electric vehicle with equal, if not superior fuel efficiency?
>
> robert luis rabello
>
>
>
>
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>
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Biofuel a

Re: [biofuels-biz] processing of waste vegetable oil...

2001-10-03 Thread steve spence

Is there any reason their plant can't use waste oil, or is it only that they
haven't?

Steve Spence
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- Original Message -
From: "Jan Sur—wka" <[EMAIL PROTECTED]>
To: 
Sent: Wednesday, October 03, 2001 3:35 AM
Subject: [biofuels-biz] processing of waste vegetable oil...


> Keith and all,
>
> You are right neither the plant from Dick Carlstein nor the one from
Poland process used oil - they
> process only virgin oils.
>
> thank you for the reminding me of this.
>
> jan surowka
>
>
>
> [EMAIL PROTECTED]
>
>
> P.S>
>
> I have no web site of  Dick Carlstein - the only thing I had was his
e-mail address.
> I was trying to e-mail him the general copy of my previous message but it
failed.
>
> regarding web site of the Polis Insitute - I do not know.
> but I was with them several times over phone and was "handed over" to the
potential producers
> with whom they have production agreements - I was advised to purchase the
plant from them.
>
> The price quoted to me was PLN 46000 i.e. about US$ 11,000 (eleven
thousand US dollars).
> If you Blair are still interested I can try to get in touch with the
Institute and try to convince them
> about selling know-how i.e. design instead of the metalwork by one of
their licencees.
>
> jan
>
>
> Biofuels at Journey to Forever
> http://journeytoforever.org/biofuel.html
> Biofuel at WebConX
> http://www.webconx.com/2000/biofuel/biofuel.htm
> To unsubscribe from this group, send an email to:
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>


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[biofuels-biz] processing of waste vegetable oil...

2001-10-03 Thread Jan Sur—wka

Keith and all,

You are right neither the plant from Dick Carlstein nor the one from Poland 
process used oil - they 
process only virgin oils.

thank you for the reminding me of this.

jan surowka



[EMAIL PROTECTED]


P.S>

I have no web site of  Dick Carlstein - the only thing I had was his e-mail 
address.
I was trying to e-mail him the general copy of my previous message but it 
failed.

regarding web site of the Polis Insitute - I do not know.
but I was with them several times over phone and was "handed over" to the 
potential producers 
with whom they have production agreements - I was advised to purchase the plant 
from them.

The price quoted to me was PLN 46000 i.e. about US$ 11,000 (eleven thousand US 
dollars).
If you Blair are still interested I can try to get in touch with the Institute 
and try to convince them 
about selling know-how i.e. design instead of the metalwork by one of their 
licencees.

jan

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RE: [biofuel] More Ballard (fuel cell)

2001-10-03 Thread kirk

How about hydride storage and for purity an aluminum molecular seive?

-Original Message-
From: robert luis rabello [mailto:[EMAIL PROTECTED]
Sent: Tuesday, October 02, 2001 11:01 PM
To: biofuel@yahoogroups.com
Subject: Re: [biofuel] More Ballard (fuel cell)




Dana Linscott wrote:

> Here is some more recent info on what I consider the
> leader in fuel cell technology. These folks are
> actually selling fuel cells right now. Major
> investments have been made in Ballard by big
> automakers in the past few years. Too much money to be
> a "red herring".
>
> http://biz.yahoo.com/mf/011002/plate_011002.html
>
> Dana

Hello Dana!

Ballard hasn't sold a single fuel cell it its history.  What they have
done is develop working prototypes, and they're selling manufacturing
licenses to interested companies.  You cannot go to Ballard and buy a fuel
cell.  (In fact, you'll have a VERY hard time getting past the reception
area!)

Yes, the auto makers are setting up license agreements, and yes, money
is
changing hands, but the money is buying control, not product.  If you read
the article you've linked to, you will learn that nobody has actually paid a
penny for a fuel cell.  Here's a quip:

"Ballard will also get a significant cash infusion from Daimler and Ford.
Combined, the automakers will invest
an additional $69 million in Ballard, which will only add to Ballard's
impressive war chest.

The automakers have extended not only their investment in Ballard, but also
their operational dependency. The
new 20-year alliance between Ballard and both Daimler and Ford will be much
simpler -- and cheaper -- than
the old alliance, and seemingly assures Ballard of customers when its
automotive fuel cells are ready for the
market, hopefully sometime in the next two to four years."

Note the word "hopefully".  Note the "two to four year" time frame.
I've
been hearing this kind of thing for a long time, and I have become quite
skeptical!

Personally, I hope Ballard can make its fuel cell technology work.  I
hope they can make a killing selling fuel cell licenses to the automobile
industry.  (Ballard is a local company up here.)  I would LOVE to see a
"hydrogen economy" come to fruition, but I've been waiting for over thirty
years for this to happen, and vexing problems remain.  The biggest one stems
from the fact that nobody has figured out the storage problem, and the PEM
fuel cells Ballard has developed require hydrogen of exceptional purity.

Steve Spence posted a link to a company a couple of days ago.  If you're
interested in hydrogen, this should intrigue you:

http://www.millenniumcell.com/solutions/white_hydrogen.html

Even with fuel cells driving electric motors, a good diesel engine is
still very hard to beat, and the technology to produce them, as well as the
infrastructure to fuel them, is already well developed.  Perhaps we should
be
exploring supplemental H2 injection in diesel engines as a way to reduce
emissions and remove the only REAL drawback to modern diesels.  Why waste
your time with fuel cells when a small diesel, driving a gen set, will power
a hybrid electric vehicle with equal, if not superior fuel efficiency?

robert luis rabello




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