Can't do that, nor would you want to for video. Your Samsung TV cannot
act as the server for anything, including SqueezeBox players.
Your TV can connect to LMS server as a simple DLNA player for music,
pics, video's on your TV.
If your TV is close enough to the PC you have running LMS, you might try
running an audio cable between them and using the 'WaveInput plugin'
(http://forums.slimdevices.com/showthread.php?35718-Announce-Wave-Input-plugin-v1-00highlight=waveinput+plugin).
Whatever audio is on the TV will now be