BBC News Science & Environment

26 January 2011 Last updated at 12:41 GMT

'Life chemicals' may have formed around far-flung star

By Jason Palmer Science and technology reporter, BBC News
Analysis of Murchison meteorite fragment Meteorites tend to contain an excess 
of left-handed amino acids
Continue reading the main story


There is now even more evidence that life on Earth may have been seeded by 
material from asteroids or comets.

Prior research has shown how amino acids - the building blocks of life - could 
form elsewhere in the cosmos.

These molecules can form in two versions, but life on Earth exclusively uses 
just one of them.

Now an Astrophysical Journal Letters paper shows how conditions around a 
far-flung star could favour the formation of one type over another.

Amino acids are corkscrew-shaped molecules that can form twisted to the left or 
right, and chemistry does not inherently favour one corkscrew direction over 
another. But without exception, life on Earth makes use of the left-handed 
version.

A famous experiment in 1952 showed how a spark across a soup of simple 
chemicals representing the primordial Earth could form amino acids - but like 
many that followed, it formed equal numbers of left- and right-handed types.

The idea that amino acids might have been delivered to the early Earth by 
meteorites - themselves formed from asteroids or comets - provided another 
route, and studies of meteorites have even shown excesses of left-handed amino 
acids.

Last week, Nasa astrobiologist Daniel Glavin and his colleagues followed up on 
that finding, saying their research showed that a wide variety of meteor types 
might play host to excesses of this sort.

What remained was to determine the mechanism by which the left-handed version 
could be preferentially produced in the cosmos, to be picked up and ultimately 
delivered to Earth.
Circular argument

Now, Uwe Meierhenrich of University of Nice Sophia Antipolis and colleagues 
have found one way that this "symmetry breaking" may happen.

They started with chunks of icy material that included several simple 
molecules: water, methanol, and ammonia - ingredients from which amino acids 
can be made.

They then exposed the ices to ultraviolet light of a very particular type.

Light has a polarisation, which is to say that light rays oscillate along a 
given direction - say, up and down, or left and right. While we can't see this 
effect directly, it is apparent in polarising sunglasses, which block reflected 
light that tends to be polarised along the left-and-right direction.

The light used by the researchers, by contrast, was what is known as circularly 
polarised. Rather than along a single direction, the polarisation traces out a 
corkscrew shape.

Light in the regions around a forming star is known to become circularly 
polarised like this as it passes through vast clouds of dust grains that are 
aligned by magnetic fields.

The experiments showed that the circularly polarised light led to the formation 
of both left- and right-handed amino acids - but there were slightly over a 
percent more of the left-handed version.

That is the level of excess that Dr Glavin and his colleagues have found in 
meteorites found on Earth - and the mechanism is a compelling fact in the case 
for an extraterrestrial origin for Earth's first amino acids.

"This excess is pretty cool," Dr Glavin told BBC News.

"You've got to break the symmetry somehow, this is critical. But how do you 
break it? That's one of the most important questions: did life just randomly 
choose one type over another? It's starting to look like Nature helped a bit."

However, Dr Glavin noted that these molecules can swap their forms, and that an 
unequal mixture of the two types will settle out to an equal mixture in time, a 
process called racemisation.

"These are exactly the kinds of experiments we need to be doing but we do need 
to keep the big picture in mind," he said.

That is, he said, to further shore up the idea that life on Earth started with 
a delivery of extraterrestrial ingredients, it still remains to pin down the 
mechanism by which the unequal mixtures can be preserved for the long journey 
from far-flung stars.
More on This Story




------------------------------------

Post message: prole...@egroups.com
Subscribe   :  proletar-subscr...@egroups.com
Unsubscribe :  proletar-unsubscr...@egroups.com
List owner  :  proletar-ow...@egroups.com
Homepage    :  http://proletar.8m.com/Yahoo! Groups Links

<*> To visit your group on the web, go to:
    http://groups.yahoo.com/group/proletar/

<*> Your email settings:
    Individual Email | Traditional

<*> To change settings online go to:
    http://groups.yahoo.com/group/proletar/join
    (Yahoo! ID required)

<*> To change settings via email:
    proletar-dig...@yahoogroups.com 
    proletar-fullfeatu...@yahoogroups.com

<*> To unsubscribe from this group, send an email to:
    proletar-unsubscr...@yahoogroups.com

<*> Your use of Yahoo! Groups is subject to:
    http://docs.yahoo.com/info/terms/

Kirim email ke