http://patft.uspto.gov/netahtml/PTO/srchnum.htm

US 6,789,548  Sept 14 2004
Method of making a smoking composition 

" The present invention relates to smoking articles such as cigarettes, and in 
particular to catalytic systems containing metallic or carbonaceous particles 
that reduce the content of certain harmful or carcinogenic substances, 
including polyaromatic hydrocarbons, tobacco-specific nitrosamines, carbazole, 
phenol, and catechol, in both mainstream cigarette smoke and side stream 
cigarette smoke."

"In preferred embodiments, the nitrate or nitrite source includes a nitrate of 
lithium, sodium, potassium, rubidium, cesium, magnesium, calcium, strontium, 
yttrium, lanthanum, cerium, neodymium, samarium, europium, gadolinium, terbium, 
dysprosium, erbium, scandium, manganese, iron, rhodium, palladium, copper, 
zinc, aluminum, gallium, tin, bismuth, hydrates thereof and mixtures thereof. 
Preferably, the nitrate salt may be an alkali or alkaline earth metal nitrate."
"One approach to removing undesired components from tobacco smoke is the use of 
catalysts. Palladium catalyst systems have been proposed for cigarettes. The 
following patents describe such systems: U.S. Pat. No. 4,257,430 to Collins et 
al.; U.S. Pat. No. 4,248,251 to Bryant et al.; U.S. Pat. No. 4,235,251 to 
Bryant et al.; U.S. Pat. No. 4,216,784 to Norman et al.; U.S. Pat. No. 
4,177,822 to Bryant et al.; and U.S. Pat. No. 4,055,191 to Norman et al., each 
of which is incorporated by reference in its entirety."

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